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Bis(3-hydroxypyridine-κN)bis(3-nitrobenzoato-κO)zinc(II)
The title complex, [Zn(C(7)H(4)NO(4))(2)(C(5)H(5)NO)(2)], has site symmetry 2. The Zn(II) ion is located on a crystallographic twofold rotation axis and assumes a distorted tetrahedral ZnN(2)O(2) coordination geometry. Molecules are linked by an intermolecular O—H⋯O hydrogen bond and π–π stacking...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977432/ https://www.ncbi.nlm.nih.gov/pubmed/21583382 http://dx.doi.org/10.1107/S1600536809027147 |
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author | Li, Jun-Hua Nie, Jing-Jing Xu, Duan-Jun |
author_facet | Li, Jun-Hua Nie, Jing-Jing Xu, Duan-Jun |
author_sort | Li, Jun-Hua |
collection | PubMed |
description | The title complex, [Zn(C(7)H(4)NO(4))(2)(C(5)H(5)NO)(2)], has site symmetry 2. The Zn(II) ion is located on a crystallographic twofold rotation axis and assumes a distorted tetrahedral ZnN(2)O(2) coordination geometry. Molecules are linked by an intermolecular O—H⋯O hydrogen bond and π–π stacking interactions between pyridine rings [centroid–centroid speparation 3.594 (1) Å]. |
format | Text |
id | pubmed-2977432 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29774322010-12-30 Bis(3-hydroxypyridine-κN)bis(3-nitrobenzoato-κO)zinc(II) Li, Jun-Hua Nie, Jing-Jing Xu, Duan-Jun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Zn(C(7)H(4)NO(4))(2)(C(5)H(5)NO)(2)], has site symmetry 2. The Zn(II) ion is located on a crystallographic twofold rotation axis and assumes a distorted tetrahedral ZnN(2)O(2) coordination geometry. Molecules are linked by an intermolecular O—H⋯O hydrogen bond and π–π stacking interactions between pyridine rings [centroid–centroid speparation 3.594 (1) Å]. International Union of Crystallography 2009-07-15 /pmc/articles/PMC2977432/ /pubmed/21583382 http://dx.doi.org/10.1107/S1600536809027147 Text en © Li et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Li, Jun-Hua Nie, Jing-Jing Xu, Duan-Jun Bis(3-hydroxypyridine-κN)bis(3-nitrobenzoato-κO)zinc(II) |
title | Bis(3-hydroxypyridine-κN)bis(3-nitrobenzoato-κO)zinc(II) |
title_full | Bis(3-hydroxypyridine-κN)bis(3-nitrobenzoato-κO)zinc(II) |
title_fullStr | Bis(3-hydroxypyridine-κN)bis(3-nitrobenzoato-κO)zinc(II) |
title_full_unstemmed | Bis(3-hydroxypyridine-κN)bis(3-nitrobenzoato-κO)zinc(II) |
title_short | Bis(3-hydroxypyridine-κN)bis(3-nitrobenzoato-κO)zinc(II) |
title_sort | bis(3-hydroxypyridine-κn)bis(3-nitrobenzoato-κo)zinc(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977432/ https://www.ncbi.nlm.nih.gov/pubmed/21583382 http://dx.doi.org/10.1107/S1600536809027147 |
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