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catena-Poly[[diaquadibromidomanganese(III)]-μ-pyridine-2-carboxylato]
The asymmetric unit of the title compound, [MnBr(2)(C(6)H(4)NO(2))(H(2)O)(2)](n), contains one monomeric unit of the neutral linear coordination polymer. The Mn(3+) ions are bridged by anionic pyridine-2-carboxylate (pic) ligands, thereby forming a chain-like structure along the c axis, and are six...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977438/ https://www.ncbi.nlm.nih.gov/pubmed/21583426 http://dx.doi.org/10.1107/S160053680902844X |
Sumario: | The asymmetric unit of the title compound, [MnBr(2)(C(6)H(4)NO(2))(H(2)O)(2)](n), contains one monomeric unit of the neutral linear coordination polymer. The Mn(3+) ions are bridged by anionic pyridine-2-carboxylate (pic) ligands, thereby forming a chain-like structure along the c axis, and are six-coordinated in a distorted octahedral environment by two O atoms of the two different carboxylate groups, two O atoms of two water molecules and two Br atoms. The complex displays intermolecular O—H⋯Br, O—H⋯N, O—H⋯O, C—H⋯O and C—H⋯Br hydrogen bonding. There may also be intermolecular π–π interactions between adjacent pyridine rings, with a centroid–centroid distance of 3.993 (8) Å. |
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