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cis-1-Ethyl-4,4,6,8-tetra­methyl-2-tosyl-2,3,3a,4,6,7,8,9-octa­hydro-1H-pyrrolo[3′,4′:3,4]pyrano[6,5-d]pyrimidine-7,9-dione

In the title compound, C(22)H(29)N(3)O(5)S, the pyrrolidine ring is cis-fused to the dihydro­pyran ring. The pyrrolidine and dihydro­pyran rings adopt twist and half-chair conformations, respectively. The mol­ecule is in a folded conformation; the sulfonyl-bound benzene ring lies over the pyrimidine...

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Autores principales: Chinnakali, K., Sudha, D., Jayagobi, M., Raghunathan, R., Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977440/
https://www.ncbi.nlm.nih.gov/pubmed/21583559
http://dx.doi.org/10.1107/S1600536809026361
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author Chinnakali, K.
Sudha, D.
Jayagobi, M.
Raghunathan, R.
Fun, Hoong-Kun
author_facet Chinnakali, K.
Sudha, D.
Jayagobi, M.
Raghunathan, R.
Fun, Hoong-Kun
author_sort Chinnakali, K.
collection PubMed
description In the title compound, C(22)H(29)N(3)O(5)S, the pyrrolidine ring is cis-fused to the dihydro­pyran ring. The pyrrolidine and dihydro­pyran rings adopt twist and half-chair conformations, respectively. The mol­ecule is in a folded conformation; the sulfonyl-bound benzene ring lies over the pyrimidine­dione ring, with a weak π–π inter­action [centroid–centroid distance = 3.6147 (4) Å]. A weak intra­molecular C—H⋯O hydrogen bond generates an S(6) ring motif. In the crystal, molecules are linked into a three-dimensional network by C—H⋯O hydrogen bonds.
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spelling pubmed-29774402010-12-30 cis-1-Ethyl-4,4,6,8-tetra­methyl-2-tosyl-2,3,3a,4,6,7,8,9-octa­hydro-1H-pyrrolo[3′,4′:3,4]pyrano[6,5-d]pyrimidine-7,9-dione Chinnakali, K. Sudha, D. Jayagobi, M. Raghunathan, R. Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(22)H(29)N(3)O(5)S, the pyrrolidine ring is cis-fused to the dihydro­pyran ring. The pyrrolidine and dihydro­pyran rings adopt twist and half-chair conformations, respectively. The mol­ecule is in a folded conformation; the sulfonyl-bound benzene ring lies over the pyrimidine­dione ring, with a weak π–π inter­action [centroid–centroid distance = 3.6147 (4) Å]. A weak intra­molecular C—H⋯O hydrogen bond generates an S(6) ring motif. In the crystal, molecules are linked into a three-dimensional network by C—H⋯O hydrogen bonds. International Union of Crystallography 2009-07-15 /pmc/articles/PMC2977440/ /pubmed/21583559 http://dx.doi.org/10.1107/S1600536809026361 Text en © Chinnakali et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Chinnakali, K.
Sudha, D.
Jayagobi, M.
Raghunathan, R.
Fun, Hoong-Kun
cis-1-Ethyl-4,4,6,8-tetra­methyl-2-tosyl-2,3,3a,4,6,7,8,9-octa­hydro-1H-pyrrolo[3′,4′:3,4]pyrano[6,5-d]pyrimidine-7,9-dione
title cis-1-Ethyl-4,4,6,8-tetra­methyl-2-tosyl-2,3,3a,4,6,7,8,9-octa­hydro-1H-pyrrolo[3′,4′:3,4]pyrano[6,5-d]pyrimidine-7,9-dione
title_full cis-1-Ethyl-4,4,6,8-tetra­methyl-2-tosyl-2,3,3a,4,6,7,8,9-octa­hydro-1H-pyrrolo[3′,4′:3,4]pyrano[6,5-d]pyrimidine-7,9-dione
title_fullStr cis-1-Ethyl-4,4,6,8-tetra­methyl-2-tosyl-2,3,3a,4,6,7,8,9-octa­hydro-1H-pyrrolo[3′,4′:3,4]pyrano[6,5-d]pyrimidine-7,9-dione
title_full_unstemmed cis-1-Ethyl-4,4,6,8-tetra­methyl-2-tosyl-2,3,3a,4,6,7,8,9-octa­hydro-1H-pyrrolo[3′,4′:3,4]pyrano[6,5-d]pyrimidine-7,9-dione
title_short cis-1-Ethyl-4,4,6,8-tetra­methyl-2-tosyl-2,3,3a,4,6,7,8,9-octa­hydro-1H-pyrrolo[3′,4′:3,4]pyrano[6,5-d]pyrimidine-7,9-dione
title_sort cis-1-ethyl-4,4,6,8-tetra­methyl-2-tosyl-2,3,3a,4,6,7,8,9-octa­hydro-1h-pyrrolo[3′,4′:3,4]pyrano[6,5-d]pyrimidine-7,9-dione
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977440/
https://www.ncbi.nlm.nih.gov/pubmed/21583559
http://dx.doi.org/10.1107/S1600536809026361
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