Cargando…
Dichlorido(2,9-dimethoxy-1,10-phenanthroline-κ(2) N,N′)zinc(II)
In the crystal structure of the title compound, [ZnCl(2)(C(14)H(12)N(2)O(2))], the Zn(II) center is four-coordinated by two N atoms from one 2,9-dimethoxy-1,10-phenanthroline ligand and two Cl atoms. The coordination geometry is distorted tetrahedral, as the Zn—N bond distances are shorter than th...
Autores principales: | , , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977442/ https://www.ncbi.nlm.nih.gov/pubmed/21583335 http://dx.doi.org/10.1107/S160053680902491X |
_version_ | 1782191109224529920 |
---|---|
author | Niu, Cao-Yuan Su, Hui Meng, Lei Kou, Chun-Hong |
author_facet | Niu, Cao-Yuan Su, Hui Meng, Lei Kou, Chun-Hong |
author_sort | Niu, Cao-Yuan |
collection | PubMed |
description | In the crystal structure of the title compound, [ZnCl(2)(C(14)H(12)N(2)O(2))], the Zn(II) center is four-coordinated by two N atoms from one 2,9-dimethoxy-1,10-phenanthroline ligand and two Cl atoms. The coordination geometry is distorted tetrahedral, as the Zn—N bond distances are shorter than the Zn—Cl distances, and the Cl—Zn—N and Cl—Zn—Cl bond angles are much larger than the N—Zn—N angle. For the ligand, the O and C atoms of the methoxy groups are almost in the plane defined by the phenanthroline ring. The two O atoms deviate from the phenanthroline mean plane by 0.076 (2) and 0.084 (2) Å, and the two methyl C atoms deviate from the phenanthroline mean plane by 0.035 (3) and 0.361 (3) Å. There are medium π–π stacking interactions between two parallel phenanthroline rings with a centroid–centroid distance of 3.7860 (2) Å and a dihedral angle between the plane defined by the two parallel phenanthroline rings of 1.13 (5)°. |
format | Text |
id | pubmed-2977442 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29774422010-12-30 Dichlorido(2,9-dimethoxy-1,10-phenanthroline-κ(2) N,N′)zinc(II) Niu, Cao-Yuan Su, Hui Meng, Lei Kou, Chun-Hong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, [ZnCl(2)(C(14)H(12)N(2)O(2))], the Zn(II) center is four-coordinated by two N atoms from one 2,9-dimethoxy-1,10-phenanthroline ligand and two Cl atoms. The coordination geometry is distorted tetrahedral, as the Zn—N bond distances are shorter than the Zn—Cl distances, and the Cl—Zn—N and Cl—Zn—Cl bond angles are much larger than the N—Zn—N angle. For the ligand, the O and C atoms of the methoxy groups are almost in the plane defined by the phenanthroline ring. The two O atoms deviate from the phenanthroline mean plane by 0.076 (2) and 0.084 (2) Å, and the two methyl C atoms deviate from the phenanthroline mean plane by 0.035 (3) and 0.361 (3) Å. There are medium π–π stacking interactions between two parallel phenanthroline rings with a centroid–centroid distance of 3.7860 (2) Å and a dihedral angle between the plane defined by the two parallel phenanthroline rings of 1.13 (5)°. International Union of Crystallography 2009-07-04 /pmc/articles/PMC2977442/ /pubmed/21583335 http://dx.doi.org/10.1107/S160053680902491X Text en © Niu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Niu, Cao-Yuan Su, Hui Meng, Lei Kou, Chun-Hong Dichlorido(2,9-dimethoxy-1,10-phenanthroline-κ(2) N,N′)zinc(II) |
title | Dichlorido(2,9-dimethoxy-1,10-phenanthroline-κ(2)
N,N′)zinc(II) |
title_full | Dichlorido(2,9-dimethoxy-1,10-phenanthroline-κ(2)
N,N′)zinc(II) |
title_fullStr | Dichlorido(2,9-dimethoxy-1,10-phenanthroline-κ(2)
N,N′)zinc(II) |
title_full_unstemmed | Dichlorido(2,9-dimethoxy-1,10-phenanthroline-κ(2)
N,N′)zinc(II) |
title_short | Dichlorido(2,9-dimethoxy-1,10-phenanthroline-κ(2)
N,N′)zinc(II) |
title_sort | dichlorido(2,9-dimethoxy-1,10-phenanthroline-κ(2)
n,n′)zinc(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977442/ https://www.ncbi.nlm.nih.gov/pubmed/21583335 http://dx.doi.org/10.1107/S160053680902491X |
work_keys_str_mv | AT niucaoyuan dichlorido29dimethoxy110phenanthrolinek2nnzincii AT suhui dichlorido29dimethoxy110phenanthrolinek2nnzincii AT menglei dichlorido29dimethoxy110phenanthrolinek2nnzincii AT kouchunhong dichlorido29dimethoxy110phenanthrolinek2nnzincii |