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Dichlorido(2,9-dimeth­oxy-1,10-phenanthroline-κ(2) N,N′)zinc(II)

In the crystal structure of the title compound, [ZnCl(2)(C(14)H(12)N(2)O(2))], the Zn(II) center is four-coordinated by two N atoms from one 2,9-dimeth­oxy-1,10-phenanthroline ligand and two Cl atoms. The coordination geometry is distorted tetra­hedral, as the Zn—N bond distances are shorter than th...

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Detalles Bibliográficos
Autores principales: Niu, Cao-Yuan, Su, Hui, Meng, Lei, Kou, Chun-Hong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977442/
https://www.ncbi.nlm.nih.gov/pubmed/21583335
http://dx.doi.org/10.1107/S160053680902491X
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author Niu, Cao-Yuan
Su, Hui
Meng, Lei
Kou, Chun-Hong
author_facet Niu, Cao-Yuan
Su, Hui
Meng, Lei
Kou, Chun-Hong
author_sort Niu, Cao-Yuan
collection PubMed
description In the crystal structure of the title compound, [ZnCl(2)(C(14)H(12)N(2)O(2))], the Zn(II) center is four-coordinated by two N atoms from one 2,9-dimeth­oxy-1,10-phenanthroline ligand and two Cl atoms. The coordination geometry is distorted tetra­hedral, as the Zn—N bond distances are shorter than the Zn—Cl distances, and the Cl—Zn—N and Cl—Zn—Cl bond angles are much larger than the N—Zn—N angle. For the ligand, the O and C atoms of the meth­oxy groups are almost in the plane defined by the phenanthroline ring. The two O atoms deviate from the phenanthroline mean plane by 0.076 (2) and 0.084 (2) Å, and the two methyl C atoms deviate from the phenanthroline mean plane by 0.035 (3) and 0.361 (3) Å. There are medium π–π stacking interactions between two parallel phenanthroline rings with a centroid–centroid distance of 3.7860 (2) Å and a dihedral angle between the plane defined by the two parallel phenanthroline rings of 1.13 (5)°.
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spelling pubmed-29774422010-12-30 Dichlorido(2,9-dimeth­oxy-1,10-phenanthroline-κ(2) N,N′)zinc(II) Niu, Cao-Yuan Su, Hui Meng, Lei Kou, Chun-Hong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, [ZnCl(2)(C(14)H(12)N(2)O(2))], the Zn(II) center is four-coordinated by two N atoms from one 2,9-dimeth­oxy-1,10-phenanthroline ligand and two Cl atoms. The coordination geometry is distorted tetra­hedral, as the Zn—N bond distances are shorter than the Zn—Cl distances, and the Cl—Zn—N and Cl—Zn—Cl bond angles are much larger than the N—Zn—N angle. For the ligand, the O and C atoms of the meth­oxy groups are almost in the plane defined by the phenanthroline ring. The two O atoms deviate from the phenanthroline mean plane by 0.076 (2) and 0.084 (2) Å, and the two methyl C atoms deviate from the phenanthroline mean plane by 0.035 (3) and 0.361 (3) Å. There are medium π–π stacking interactions between two parallel phenanthroline rings with a centroid–centroid distance of 3.7860 (2) Å and a dihedral angle between the plane defined by the two parallel phenanthroline rings of 1.13 (5)°. International Union of Crystallography 2009-07-04 /pmc/articles/PMC2977442/ /pubmed/21583335 http://dx.doi.org/10.1107/S160053680902491X Text en © Niu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Niu, Cao-Yuan
Su, Hui
Meng, Lei
Kou, Chun-Hong
Dichlorido(2,9-dimeth­oxy-1,10-phenanthroline-κ(2) N,N′)zinc(II)
title Dichlorido(2,9-dimeth­oxy-1,10-phenanthroline-κ(2) N,N′)zinc(II)
title_full Dichlorido(2,9-dimeth­oxy-1,10-phenanthroline-κ(2) N,N′)zinc(II)
title_fullStr Dichlorido(2,9-dimeth­oxy-1,10-phenanthroline-κ(2) N,N′)zinc(II)
title_full_unstemmed Dichlorido(2,9-dimeth­oxy-1,10-phenanthroline-κ(2) N,N′)zinc(II)
title_short Dichlorido(2,9-dimeth­oxy-1,10-phenanthroline-κ(2) N,N′)zinc(II)
title_sort dichlorido(2,9-dimeth­oxy-1,10-phenanthroline-κ(2) n,n′)zinc(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977442/
https://www.ncbi.nlm.nih.gov/pubmed/21583335
http://dx.doi.org/10.1107/S160053680902491X
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