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4-(Dimethylamino)pyridinium tribromido{3-[bromo/hydro(0.9/0.1)]-4-(dimethylamino)pyridine-κN (1)}cobaltate(II)
The reaction of a cobalt(II) salt with 4-(dimethylamino)pyridinium hydrobromide perbromide yielded the title compound, (C(7)H(11)N(2))[CoBr(3)(C(7)H(9.1)Br(0.9)N(2))]. In the anion, the Co(II) atom is coordinated in a distorted tetrahedral geometry by three Br atoms and the pyridine N atom of a b...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977443/ https://www.ncbi.nlm.nih.gov/pubmed/21583405 http://dx.doi.org/10.1107/S1600536809027913 |
Sumario: | The reaction of a cobalt(II) salt with 4-(dimethylamino)pyridinium hydrobromide perbromide yielded the title compound, (C(7)H(11)N(2))[CoBr(3)(C(7)H(9.1)Br(0.9)N(2))]. In the anion, the Co(II) atom is coordinated in a distorted tetrahedral geometry by three Br atoms and the pyridine N atom of a bromine-substituted 4-(dimethylamino)pyridine molecule, whose formation probably results from an incomplete substitution (90%) catalysed by the Co(II) ion. One of the three bromine atoms bonded to the metal is disordered over two sites in a 0.9:0.1 ratio. An N—H⋯Br hydrogen bond connects the cation and anion. |
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