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4-(Dimethyl­amino)pyridinium tri­bromido­{3-[bromo/hydro­(0.9/0.1)]-4-(dimethyl­amino)pyridine-κN (1)}cobaltate(II)

The reaction of a cobalt(II) salt with 4-(dimethyl­amino)pyridinium hydro­bromide perbromide yielded the title compound, (C(7)H(11)N(2))[CoBr(3)(C(7)H(9.1)Br(0.9)N(2))]. In the anion, the Co(II) atom is coordinated in a distorted tetra­hedral geometry by three Br atoms and the pyridine N atom of a b...

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Detalles Bibliográficos
Autores principales: Lo, Kong Mun, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977443/
https://www.ncbi.nlm.nih.gov/pubmed/21583405
http://dx.doi.org/10.1107/S1600536809027913
Descripción
Sumario:The reaction of a cobalt(II) salt with 4-(dimethyl­amino)pyridinium hydro­bromide perbromide yielded the title compound, (C(7)H(11)N(2))[CoBr(3)(C(7)H(9.1)Br(0.9)N(2))]. In the anion, the Co(II) atom is coordinated in a distorted tetra­hedral geometry by three Br atoms and the pyridine N atom of a bromine-substituted 4-(dimethyl­amino)pyridine mol­ecule, whose formation probably results from an incomplete substitution (90%) catalysed by the Co(II) ion. One of the three bromine atoms bonded to the metal is disordered over two sites in a 0.9:0.1 ratio. An N—H⋯Br hydrogen bond connects the cation and anion.