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Tetra­aqua­(5,5′-dimethyl-2,2′-bipyridine-κ(2) N,N′)zinc(II) sulfate

The asymmetric unit of the title compound, [Zn(C(12)H(12)N(2))(H(2)O)(4)]SO(4), consists of a Zn(II) complex cation, a sulfate anion and four mol­ecules of water coordinated to the Zn(II) atom. The Zn(II) complex cation, with approximate twofold symmetry, displays a slightly distorted octa­hedral ge...

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Detalles Bibliográficos
Autores principales: Zhao, Qing-Lan, Bai, Hui-Feng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977444/
https://www.ncbi.nlm.nih.gov/pubmed/21583333
http://dx.doi.org/10.1107/S160053680902488X
Descripción
Sumario:The asymmetric unit of the title compound, [Zn(C(12)H(12)N(2))(H(2)O)(4)]SO(4), consists of a Zn(II) complex cation, a sulfate anion and four mol­ecules of water coordinated to the Zn(II) atom. The Zn(II) complex cation, with approximate twofold symmetry, displays a slightly distorted octa­hedral geometry around the Zn(II) atom, which is coordinated by two N atoms from a 5,5′-dimethyl-2,2′-bipyridine ligand and by the O atoms of four water mol­ecules. In the crystal, O—H⋯O hydrogen bonds help to establish the packing.