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Tetraaqua(5,5′-dimethyl-2,2′-bipyridine-κ(2) N,N′)zinc(II) sulfate
The asymmetric unit of the title compound, [Zn(C(12)H(12)N(2))(H(2)O)(4)]SO(4), consists of a Zn(II) complex cation, a sulfate anion and four molecules of water coordinated to the Zn(II) atom. The Zn(II) complex cation, with approximate twofold symmetry, displays a slightly distorted octahedral ge...
| Autores principales: | , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977444/ https://www.ncbi.nlm.nih.gov/pubmed/21583333 http://dx.doi.org/10.1107/S160053680902488X |
| _version_ | 1782191109696389120 |
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| author | Zhao, Qing-Lan Bai, Hui-Feng |
| author_facet | Zhao, Qing-Lan Bai, Hui-Feng |
| author_sort | Zhao, Qing-Lan |
| collection | PubMed |
| description | The asymmetric unit of the title compound, [Zn(C(12)H(12)N(2))(H(2)O)(4)]SO(4), consists of a Zn(II) complex cation, a sulfate anion and four molecules of water coordinated to the Zn(II) atom. The Zn(II) complex cation, with approximate twofold symmetry, displays a slightly distorted octahedral geometry around the Zn(II) atom, which is coordinated by two N atoms from a 5,5′-dimethyl-2,2′-bipyridine ligand and by the O atoms of four water molecules. In the crystal, O—H⋯O hydrogen bonds help to establish the packing. |
| format | Text |
| id | pubmed-2977444 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29774442010-12-30 Tetraaqua(5,5′-dimethyl-2,2′-bipyridine-κ(2) N,N′)zinc(II) sulfate Zhao, Qing-Lan Bai, Hui-Feng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Zn(C(12)H(12)N(2))(H(2)O)(4)]SO(4), consists of a Zn(II) complex cation, a sulfate anion and four molecules of water coordinated to the Zn(II) atom. The Zn(II) complex cation, with approximate twofold symmetry, displays a slightly distorted octahedral geometry around the Zn(II) atom, which is coordinated by two N atoms from a 5,5′-dimethyl-2,2′-bipyridine ligand and by the O atoms of four water molecules. In the crystal, O—H⋯O hydrogen bonds help to establish the packing. International Union of Crystallography 2009-07-04 /pmc/articles/PMC2977444/ /pubmed/21583333 http://dx.doi.org/10.1107/S160053680902488X Text en © Zhao and Bai 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Zhao, Qing-Lan Bai, Hui-Feng Tetraaqua(5,5′-dimethyl-2,2′-bipyridine-κ(2) N,N′)zinc(II) sulfate |
| title | Tetraaqua(5,5′-dimethyl-2,2′-bipyridine-κ(2)
N,N′)zinc(II) sulfate |
| title_full | Tetraaqua(5,5′-dimethyl-2,2′-bipyridine-κ(2)
N,N′)zinc(II) sulfate |
| title_fullStr | Tetraaqua(5,5′-dimethyl-2,2′-bipyridine-κ(2)
N,N′)zinc(II) sulfate |
| title_full_unstemmed | Tetraaqua(5,5′-dimethyl-2,2′-bipyridine-κ(2)
N,N′)zinc(II) sulfate |
| title_short | Tetraaqua(5,5′-dimethyl-2,2′-bipyridine-κ(2)
N,N′)zinc(II) sulfate |
| title_sort | tetraaqua(5,5′-dimethyl-2,2′-bipyridine-κ(2)
n,n′)zinc(ii) sulfate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977444/ https://www.ncbi.nlm.nih.gov/pubmed/21583333 http://dx.doi.org/10.1107/S160053680902488X |
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