Tetra­kis(2-amino-6-methyl­pyridinium) hexa­chloridobismuthate(III) chloride monohydrate

The asymmetric unit of the title compound, (C(6)H(9)N(2))(4)[BiCl(6)]Cl·H(2)O, contains four protonated 2-amino-6-methyl­pyridine (HAMP) cations and two-halves of two [BiCl(6)](3−) anions, together with one water mol­ecule and one chloride anion. The Bi(III) atoms are hexa­coordinated by Cl atoms, f...

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Detalles Bibliográficos
Autores principales: Yang, Zhen, Chen, Gang, Xu, Wei, Fan, Zheng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977446/
https://www.ncbi.nlm.nih.gov/pubmed/21583350
http://dx.doi.org/10.1107/S1600536809025446
Descripción
Sumario:The asymmetric unit of the title compound, (C(6)H(9)N(2))(4)[BiCl(6)]Cl·H(2)O, contains four protonated 2-amino-6-methyl­pyridine (HAMP) cations and two-halves of two [BiCl(6)](3−) anions, together with one water mol­ecule and one chloride anion. The Bi(III) atoms are hexa­coordinated by Cl atoms, forming distorted octa­hedral geometries. In the crystal structure, intra­molecular O—H⋯Cl and N—H⋯Cl, and inter­molecular O—H⋯Cl and N—H⋯O inter­actions link the mol­ecules into a three-dimensional network.

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