Tetra­kis(2-amino-6-methyl­pyridinium) hexa­chloridobismuthate(III) chloride monohydrate

The asymmetric unit of the title compound, (C(6)H(9)N(2))(4)[BiCl(6)]Cl·H(2)O, contains four protonated 2-amino-6-methyl­pyridine (HAMP) cations and two-halves of two [BiCl(6)](3−) anions, together with one water mol­ecule and one chloride anion. The Bi(III) atoms are hexa­coordinated by Cl atoms, f...

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Detalles Bibliográficos
Autores principales: Yang, Zhen, Chen, Gang, Xu, Wei, Fan, Zheng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977446/
https://www.ncbi.nlm.nih.gov/pubmed/21583350
http://dx.doi.org/10.1107/S1600536809025446
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author Yang, Zhen
Chen, Gang
Xu, Wei
Fan, Zheng
author_facet Yang, Zhen
Chen, Gang
Xu, Wei
Fan, Zheng
author_sort Yang, Zhen
collection PubMed
description The asymmetric unit of the title compound, (C(6)H(9)N(2))(4)[BiCl(6)]Cl·H(2)O, contains four protonated 2-amino-6-methyl­pyridine (HAMP) cations and two-halves of two [BiCl(6)](3−) anions, together with one water mol­ecule and one chloride anion. The Bi(III) atoms are hexa­coordinated by Cl atoms, forming distorted octa­hedral geometries. In the crystal structure, intra­molecular O—H⋯Cl and N—H⋯Cl, and inter­molecular O—H⋯Cl and N—H⋯O inter­actions link the mol­ecules into a three-dimensional network.
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spelling pubmed-29774462010-12-30 Tetra­kis(2-amino-6-methyl­pyridinium) hexa­chloridobismuthate(III) chloride monohydrate Yang, Zhen Chen, Gang Xu, Wei Fan, Zheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, (C(6)H(9)N(2))(4)[BiCl(6)]Cl·H(2)O, contains four protonated 2-amino-6-methyl­pyridine (HAMP) cations and two-halves of two [BiCl(6)](3−) anions, together with one water mol­ecule and one chloride anion. The Bi(III) atoms are hexa­coordinated by Cl atoms, forming distorted octa­hedral geometries. In the crystal structure, intra­molecular O—H⋯Cl and N—H⋯Cl, and inter­molecular O—H⋯Cl and N—H⋯O inter­actions link the mol­ecules into a three-dimensional network. International Union of Crystallography 2009-07-08 /pmc/articles/PMC2977446/ /pubmed/21583350 http://dx.doi.org/10.1107/S1600536809025446 Text en © Yang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yang, Zhen
Chen, Gang
Xu, Wei
Fan, Zheng
Tetra­kis(2-amino-6-methyl­pyridinium) hexa­chloridobismuthate(III) chloride monohydrate
title Tetra­kis(2-amino-6-methyl­pyridinium) hexa­chloridobismuthate(III) chloride monohydrate
title_full Tetra­kis(2-amino-6-methyl­pyridinium) hexa­chloridobismuthate(III) chloride monohydrate
title_fullStr Tetra­kis(2-amino-6-methyl­pyridinium) hexa­chloridobismuthate(III) chloride monohydrate
title_full_unstemmed Tetra­kis(2-amino-6-methyl­pyridinium) hexa­chloridobismuthate(III) chloride monohydrate
title_short Tetra­kis(2-amino-6-methyl­pyridinium) hexa­chloridobismuthate(III) chloride monohydrate
title_sort tetra­kis(2-amino-6-methyl­pyridinium) hexa­chloridobismuthate(iii) chloride monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977446/
https://www.ncbi.nlm.nih.gov/pubmed/21583350
http://dx.doi.org/10.1107/S1600536809025446
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AT xuwei tetrakis2amino6methylpyridiniumhexachloridobismuthateiiichloridemonohydrate
AT fanzheng tetrakis2amino6methylpyridiniumhexachloridobismuthateiiichloridemonohydrate

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