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Aqua­(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)bis­(3-hydroxy­benzoato-κO)manganese(II)–2,9-dimethyl-1,10-phenanthroline–water (1/1/1)

In the title compound, [Mn(C(7)H(5)O(3))(2)(C(14)H(12)N(2))(H(2)O)]·C(14)H(12)N(2)·H(2)O, the Mn(II) ion is coordinated by a bidentate 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand, two monodentate 3-hydroxy­benzoate anions (3-HBA) and one water mol­ecule in a distorted trigonal-bipyramidal envir...

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Detalles Bibliográficos
Autores principales: Liu, Xuejun, Jin, Linyu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977455/
https://www.ncbi.nlm.nih.gov/pubmed/21583361
http://dx.doi.org/10.1107/S1600536809025926
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author Liu, Xuejun
Jin, Linyu
author_facet Liu, Xuejun
Jin, Linyu
author_sort Liu, Xuejun
collection PubMed
description In the title compound, [Mn(C(7)H(5)O(3))(2)(C(14)H(12)N(2))(H(2)O)]·C(14)H(12)N(2)·H(2)O, the Mn(II) ion is coordinated by a bidentate 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand, two monodentate 3-hydroxy­benzoate anions (3-HBA) and one water mol­ecule in a distorted trigonal-bipyramidal environment. An uncoordinated dmphen and an uncoordinated water mol­ecule cocrystallized with each complex mol­ecule. Intra- and inter­molecular O—H⋯N and O—H⋯O hydrogen bonds are also present between the coordinated 3-HBA and water mol­ecules and the uncoordinated dmphen and water mol­ecules in the crystal. The packing of the structure is further stabilized by π–π stacking inter­actions involving dmphen mol­ecules, with a centroid–centroid separation of 3.705 (3) Å.
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spelling pubmed-29774552010-12-30 Aqua­(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)bis­(3-hydroxy­benzoato-κO)manganese(II)–2,9-dimethyl-1,10-phenanthroline–water (1/1/1) Liu, Xuejun Jin, Linyu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Mn(C(7)H(5)O(3))(2)(C(14)H(12)N(2))(H(2)O)]·C(14)H(12)N(2)·H(2)O, the Mn(II) ion is coordinated by a bidentate 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand, two monodentate 3-hydroxy­benzoate anions (3-HBA) and one water mol­ecule in a distorted trigonal-bipyramidal environment. An uncoordinated dmphen and an uncoordinated water mol­ecule cocrystallized with each complex mol­ecule. Intra- and inter­molecular O—H⋯N and O—H⋯O hydrogen bonds are also present between the coordinated 3-HBA and water mol­ecules and the uncoordinated dmphen and water mol­ecules in the crystal. The packing of the structure is further stabilized by π–π stacking inter­actions involving dmphen mol­ecules, with a centroid–centroid separation of 3.705 (3) Å. International Union of Crystallography 2009-07-11 /pmc/articles/PMC2977455/ /pubmed/21583361 http://dx.doi.org/10.1107/S1600536809025926 Text en © Liu and Jin 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Xuejun
Jin, Linyu
Aqua­(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)bis­(3-hydroxy­benzoato-κO)manganese(II)–2,9-dimethyl-1,10-phenanthroline–water (1/1/1)
title Aqua­(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)bis­(3-hydroxy­benzoato-κO)manganese(II)–2,9-dimethyl-1,10-phenanthroline–water (1/1/1)
title_full Aqua­(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)bis­(3-hydroxy­benzoato-κO)manganese(II)–2,9-dimethyl-1,10-phenanthroline–water (1/1/1)
title_fullStr Aqua­(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)bis­(3-hydroxy­benzoato-κO)manganese(II)–2,9-dimethyl-1,10-phenanthroline–water (1/1/1)
title_full_unstemmed Aqua­(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)bis­(3-hydroxy­benzoato-κO)manganese(II)–2,9-dimethyl-1,10-phenanthroline–water (1/1/1)
title_short Aqua­(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)bis­(3-hydroxy­benzoato-κO)manganese(II)–2,9-dimethyl-1,10-phenanthroline–water (1/1/1)
title_sort aqua­(2,9-dimethyl-1,10-phenanthroline-κ(2) n,n′)bis­(3-hydroxy­benzoato-κo)manganese(ii)–2,9-dimethyl-1,10-phenanthroline–water (1/1/1)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977455/
https://www.ncbi.nlm.nih.gov/pubmed/21583361
http://dx.doi.org/10.1107/S1600536809025926
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