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Aqua(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)bis(3-hydroxybenzoato-κO)manganese(II)–2,9-dimethyl-1,10-phenanthroline–water (1/1/1)
In the title compound, [Mn(C(7)H(5)O(3))(2)(C(14)H(12)N(2))(H(2)O)]·C(14)H(12)N(2)·H(2)O, the Mn(II) ion is coordinated by a bidentate 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand, two monodentate 3-hydroxybenzoate anions (3-HBA) and one water molecule in a distorted trigonal-bipyramidal envir...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977455/ https://www.ncbi.nlm.nih.gov/pubmed/21583361 http://dx.doi.org/10.1107/S1600536809025926 |
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author | Liu, Xuejun Jin, Linyu |
author_facet | Liu, Xuejun Jin, Linyu |
author_sort | Liu, Xuejun |
collection | PubMed |
description | In the title compound, [Mn(C(7)H(5)O(3))(2)(C(14)H(12)N(2))(H(2)O)]·C(14)H(12)N(2)·H(2)O, the Mn(II) ion is coordinated by a bidentate 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand, two monodentate 3-hydroxybenzoate anions (3-HBA) and one water molecule in a distorted trigonal-bipyramidal environment. An uncoordinated dmphen and an uncoordinated water molecule cocrystallized with each complex molecule. Intra- and intermolecular O—H⋯N and O—H⋯O hydrogen bonds are also present between the coordinated 3-HBA and water molecules and the uncoordinated dmphen and water molecules in the crystal. The packing of the structure is further stabilized by π–π stacking interactions involving dmphen molecules, with a centroid–centroid separation of 3.705 (3) Å. |
format | Text |
id | pubmed-2977455 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29774552010-12-30 Aqua(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)bis(3-hydroxybenzoato-κO)manganese(II)–2,9-dimethyl-1,10-phenanthroline–water (1/1/1) Liu, Xuejun Jin, Linyu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Mn(C(7)H(5)O(3))(2)(C(14)H(12)N(2))(H(2)O)]·C(14)H(12)N(2)·H(2)O, the Mn(II) ion is coordinated by a bidentate 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand, two monodentate 3-hydroxybenzoate anions (3-HBA) and one water molecule in a distorted trigonal-bipyramidal environment. An uncoordinated dmphen and an uncoordinated water molecule cocrystallized with each complex molecule. Intra- and intermolecular O—H⋯N and O—H⋯O hydrogen bonds are also present between the coordinated 3-HBA and water molecules and the uncoordinated dmphen and water molecules in the crystal. The packing of the structure is further stabilized by π–π stacking interactions involving dmphen molecules, with a centroid–centroid separation of 3.705 (3) Å. International Union of Crystallography 2009-07-11 /pmc/articles/PMC2977455/ /pubmed/21583361 http://dx.doi.org/10.1107/S1600536809025926 Text en © Liu and Jin 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Liu, Xuejun Jin, Linyu Aqua(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)bis(3-hydroxybenzoato-κO)manganese(II)–2,9-dimethyl-1,10-phenanthroline–water (1/1/1) |
title | Aqua(2,9-dimethyl-1,10-phenanthroline-κ(2)
N,N′)bis(3-hydroxybenzoato-κO)manganese(II)–2,9-dimethyl-1,10-phenanthroline–water (1/1/1) |
title_full | Aqua(2,9-dimethyl-1,10-phenanthroline-κ(2)
N,N′)bis(3-hydroxybenzoato-κO)manganese(II)–2,9-dimethyl-1,10-phenanthroline–water (1/1/1) |
title_fullStr | Aqua(2,9-dimethyl-1,10-phenanthroline-κ(2)
N,N′)bis(3-hydroxybenzoato-κO)manganese(II)–2,9-dimethyl-1,10-phenanthroline–water (1/1/1) |
title_full_unstemmed | Aqua(2,9-dimethyl-1,10-phenanthroline-κ(2)
N,N′)bis(3-hydroxybenzoato-κO)manganese(II)–2,9-dimethyl-1,10-phenanthroline–water (1/1/1) |
title_short | Aqua(2,9-dimethyl-1,10-phenanthroline-κ(2)
N,N′)bis(3-hydroxybenzoato-κO)manganese(II)–2,9-dimethyl-1,10-phenanthroline–water (1/1/1) |
title_sort | aqua(2,9-dimethyl-1,10-phenanthroline-κ(2)
n,n′)bis(3-hydroxybenzoato-κo)manganese(ii)–2,9-dimethyl-1,10-phenanthroline–water (1/1/1) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977455/ https://www.ncbi.nlm.nih.gov/pubmed/21583361 http://dx.doi.org/10.1107/S1600536809025926 |
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