Bis{(E)-4-bromo-2-[(2-chloro-3-pyrid­yl)imino­meth­yl]phenolato-κ(2) N,O}copper(II)

In the title complex, [Cu(C(12)H(7)BrClN(2)O)(2)], the Cu(II) center is tetra­coordinated by two phenolate O and two azomethine N atoms from two independent bidentate 4-bromo-2-[(2-chloro-3-pyrid­yl)imino­meth­yl]phenolate (L) ligands. In the crystal structure, the Cu(II) atom has a distorted square...

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Autores principales: Dong, Wen-Kui, Tong, Jun-Feng, An, Li-Li, Wu, Jian-Chao, Yao, Jian
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977463/
https://www.ncbi.nlm.nih.gov/pubmed/21583395
http://dx.doi.org/10.1107/S1600536809027792
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author Dong, Wen-Kui
Tong, Jun-Feng
An, Li-Li
Wu, Jian-Chao
Yao, Jian
author_facet Dong, Wen-Kui
Tong, Jun-Feng
An, Li-Li
Wu, Jian-Chao
Yao, Jian
author_sort Dong, Wen-Kui
collection PubMed
description In the title complex, [Cu(C(12)H(7)BrClN(2)O)(2)], the Cu(II) center is tetra­coordinated by two phenolate O and two azomethine N atoms from two independent bidentate 4-bromo-2-[(2-chloro-3-pyrid­yl)imino­meth­yl]phenolate (L) ligands. In the crystal structure, the Cu(II) atom has a distorted square-planar coordination environment. The inter­planar dihedral angles between the benzene and pyridine rings in the individual ligands are 63.83 (4) and 54.43 (3)°, indicating the pyridine ring to have considerably weaker steric hindrance.
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spelling pubmed-29774632010-12-30 Bis{(E)-4-bromo-2-[(2-chloro-3-pyrid­yl)imino­meth­yl]phenolato-κ(2) N,O}copper(II) Dong, Wen-Kui Tong, Jun-Feng An, Li-Li Wu, Jian-Chao Yao, Jian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cu(C(12)H(7)BrClN(2)O)(2)], the Cu(II) center is tetra­coordinated by two phenolate O and two azomethine N atoms from two independent bidentate 4-bromo-2-[(2-chloro-3-pyrid­yl)imino­meth­yl]phenolate (L) ligands. In the crystal structure, the Cu(II) atom has a distorted square-planar coordination environment. The inter­planar dihedral angles between the benzene and pyridine rings in the individual ligands are 63.83 (4) and 54.43 (3)°, indicating the pyridine ring to have considerably weaker steric hindrance. International Union of Crystallography 2009-07-18 /pmc/articles/PMC2977463/ /pubmed/21583395 http://dx.doi.org/10.1107/S1600536809027792 Text en © Dong et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Dong, Wen-Kui
Tong, Jun-Feng
An, Li-Li
Wu, Jian-Chao
Yao, Jian
Bis{(E)-4-bromo-2-[(2-chloro-3-pyrid­yl)imino­meth­yl]phenolato-κ(2) N,O}copper(II)
title Bis{(E)-4-bromo-2-[(2-chloro-3-pyrid­yl)imino­meth­yl]phenolato-κ(2) N,O}copper(II)
title_full Bis{(E)-4-bromo-2-[(2-chloro-3-pyrid­yl)imino­meth­yl]phenolato-κ(2) N,O}copper(II)
title_fullStr Bis{(E)-4-bromo-2-[(2-chloro-3-pyrid­yl)imino­meth­yl]phenolato-κ(2) N,O}copper(II)
title_full_unstemmed Bis{(E)-4-bromo-2-[(2-chloro-3-pyrid­yl)imino­meth­yl]phenolato-κ(2) N,O}copper(II)
title_short Bis{(E)-4-bromo-2-[(2-chloro-3-pyrid­yl)imino­meth­yl]phenolato-κ(2) N,O}copper(II)
title_sort bis{(e)-4-bromo-2-[(2-chloro-3-pyrid­yl)imino­meth­yl]phenolato-κ(2) n,o}copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977463/
https://www.ncbi.nlm.nih.gov/pubmed/21583395
http://dx.doi.org/10.1107/S1600536809027792
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