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1(2,3),2(3,2),3(2,3),4(3,2)-Tetrakis(1-benzothiophena)cyclotetraphane benzene sesquisolvate
In the title compound, C(32)H(16)S(4)·1.5C(6)H(6), the substituted cyclooctatetraene (COT) ring compound has approximate local D (2) point symmetry of the so-called ‘saddle’ form: the dihedral angles between neighboring benzo[b]thiophene units are 61.33 (4), 61.61 (4), 56.443 (14) and 58.32 (4)°...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977466/ https://www.ncbi.nlm.nih.gov/pubmed/21583541 http://dx.doi.org/10.1107/S1600536809026178 |
| _version_ | 1782191114915151872 |
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| author | Wang, Zhi-Hua Shi, Jian-Wu Zhu, Sheng Wang, Hua |
| author_facet | Wang, Zhi-Hua Shi, Jian-Wu Zhu, Sheng Wang, Hua |
| author_sort | Wang, Zhi-Hua |
| collection | PubMed |
| description | In the title compound, C(32)H(16)S(4)·1.5C(6)H(6), the substituted cyclooctatetraene (COT) ring compound has approximate local D (2) point symmetry of the so-called ‘saddle’ form: the dihedral angles between neighboring benzo[b]thiophene units are 61.33 (4), 61.61 (4), 56.443 (14) and 58.32 (4)°. The short distance [3.545 (1) Å] between an S atom and the centroid of a benzene ring in a neighboring molecule may indicate S⋯π interactions in the crystal. |
| format | Text |
| id | pubmed-2977466 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29774662010-12-30 1(2,3),2(3,2),3(2,3),4(3,2)-Tetrakis(1-benzothiophena)cyclotetraphane benzene sesquisolvate Wang, Zhi-Hua Shi, Jian-Wu Zhu, Sheng Wang, Hua Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(32)H(16)S(4)·1.5C(6)H(6), the substituted cyclooctatetraene (COT) ring compound has approximate local D (2) point symmetry of the so-called ‘saddle’ form: the dihedral angles between neighboring benzo[b]thiophene units are 61.33 (4), 61.61 (4), 56.443 (14) and 58.32 (4)°. The short distance [3.545 (1) Å] between an S atom and the centroid of a benzene ring in a neighboring molecule may indicate S⋯π interactions in the crystal. International Union of Crystallography 2009-07-11 /pmc/articles/PMC2977466/ /pubmed/21583541 http://dx.doi.org/10.1107/S1600536809026178 Text en © Wang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers Wang, Zhi-Hua Shi, Jian-Wu Zhu, Sheng Wang, Hua 1(2,3),2(3,2),3(2,3),4(3,2)-Tetrakis(1-benzothiophena)cyclotetraphane benzene sesquisolvate |
| title | 1(2,3),2(3,2),3(2,3),4(3,2)-Tetrakis(1-benzothiophena)cyclotetraphane benzene sesquisolvate |
| title_full | 1(2,3),2(3,2),3(2,3),4(3,2)-Tetrakis(1-benzothiophena)cyclotetraphane benzene sesquisolvate |
| title_fullStr | 1(2,3),2(3,2),3(2,3),4(3,2)-Tetrakis(1-benzothiophena)cyclotetraphane benzene sesquisolvate |
| title_full_unstemmed | 1(2,3),2(3,2),3(2,3),4(3,2)-Tetrakis(1-benzothiophena)cyclotetraphane benzene sesquisolvate |
| title_short | 1(2,3),2(3,2),3(2,3),4(3,2)-Tetrakis(1-benzothiophena)cyclotetraphane benzene sesquisolvate |
| title_sort | 1(2,3),2(3,2),3(2,3),4(3,2)-tetrakis(1-benzothiophena)cyclotetraphane benzene sesquisolvate |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977466/ https://www.ncbi.nlm.nih.gov/pubmed/21583541 http://dx.doi.org/10.1107/S1600536809026178 |
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