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Aqua(2,2′-bipyridine)bis(4-hydroxybenzoato)zinc(II)
In the title complex, [Zn(C(7)H(5)O(3))(2)(C(10)H(8)N(2))(H(2)O)], the Zn(II) ion is coordinated by two 4-hydroxybenzoate anions, one 2,2′-bipyridine molecule and one water molecule and displays a distorted octahedral geometry. One Zn—O bond [2.5300 (15) Å] is much longer than the others in the...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977467/ https://www.ncbi.nlm.nih.gov/pubmed/21583344 http://dx.doi.org/10.1107/S1600536809025525 |
| _version_ | 1782191115156324352 |
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| author | Zhang, Bing-Yu Nie, Jing-Jing Xu, Duan-Jun |
| author_facet | Zhang, Bing-Yu Nie, Jing-Jing Xu, Duan-Jun |
| author_sort | Zhang, Bing-Yu |
| collection | PubMed |
| description | In the title complex, [Zn(C(7)H(5)O(3))(2)(C(10)H(8)N(2))(H(2)O)], the Zn(II) ion is coordinated by two 4-hydroxybenzoate anions, one 2,2′-bipyridine molecule and one water molecule and displays a distorted octahedral geometry. One Zn—O bond [2.5300 (15) Å] is much longer than the others in the molecule. In the crystal structure, the face-to-face separation of 3.547 (9) Å suggests no π–π stacking between parallel bipyridine ring systems, and an extensive O—H⋯O hydrogen-bonding network between the coordinated water molecule, the phenol group and carboxylate O atoms is present. |
| format | Text |
| id | pubmed-2977467 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29774672010-12-30 Aqua(2,2′-bipyridine)bis(4-hydroxybenzoato)zinc(II) Zhang, Bing-Yu Nie, Jing-Jing Xu, Duan-Jun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Zn(C(7)H(5)O(3))(2)(C(10)H(8)N(2))(H(2)O)], the Zn(II) ion is coordinated by two 4-hydroxybenzoate anions, one 2,2′-bipyridine molecule and one water molecule and displays a distorted octahedral geometry. One Zn—O bond [2.5300 (15) Å] is much longer than the others in the molecule. In the crystal structure, the face-to-face separation of 3.547 (9) Å suggests no π–π stacking between parallel bipyridine ring systems, and an extensive O—H⋯O hydrogen-bonding network between the coordinated water molecule, the phenol group and carboxylate O atoms is present. International Union of Crystallography 2009-07-08 /pmc/articles/PMC2977467/ /pubmed/21583344 http://dx.doi.org/10.1107/S1600536809025525 Text en © Zhang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Zhang, Bing-Yu Nie, Jing-Jing Xu, Duan-Jun Aqua(2,2′-bipyridine)bis(4-hydroxybenzoato)zinc(II) |
| title | Aqua(2,2′-bipyridine)bis(4-hydroxybenzoato)zinc(II) |
| title_full | Aqua(2,2′-bipyridine)bis(4-hydroxybenzoato)zinc(II) |
| title_fullStr | Aqua(2,2′-bipyridine)bis(4-hydroxybenzoato)zinc(II) |
| title_full_unstemmed | Aqua(2,2′-bipyridine)bis(4-hydroxybenzoato)zinc(II) |
| title_short | Aqua(2,2′-bipyridine)bis(4-hydroxybenzoato)zinc(II) |
| title_sort | aqua(2,2′-bipyridine)bis(4-hydroxybenzoato)zinc(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977467/ https://www.ncbi.nlm.nih.gov/pubmed/21583344 http://dx.doi.org/10.1107/S1600536809025525 |
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