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3-Methyl-3,4-dihydro-9H-carbazol-1(2H)-one
In the title molecule, C(13)H(13)NO, the dihedral angle between the benzene ring and the fused pyrrole ring is 2.03 (5)°. The methyl group at the 3-position has an equatorial orientation. The cyclohexene ring adopts an envelope conformation. Three C atoms of the cyclohexene ring, with their attac...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977477/ https://www.ncbi.nlm.nih.gov/pubmed/21583627 http://dx.doi.org/10.1107/S1600536809028050 |
Sumario: | In the title molecule, C(13)H(13)NO, the dihedral angle between the benzene ring and the fused pyrrole ring is 2.03 (5)°. The methyl group at the 3-position has an equatorial orientation. The cyclohexene ring adopts an envelope conformation. Three C atoms of the cyclohexene ring, with their attached H atoms, and all atoms of the methyl group are disordered over two positions, the site-occupancy factors being 0.883 (2) and 0.117 (2). In the crystal structure, molecules are stabilized by intermolecular N—H⋯O hydrogen bonds. A C—H⋯π interaction, involving the benzene ring, is also found. |
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