N-(3,4-Dichloro­phen­yl)-2,4-dimethyl­benzene­sulfonamide

In the crystal structure of the title compound, C(14)H(13)Cl(2)NO(2)S, the configurations of the N—C bond with respect to the S=O bonds are trans and gauche. The mol­ecule is bent at the S atom with a C—SO(2)—NH—C torsion angle of −69.7 (2)°. The conformation of the N—H bond is syn to the 3-chloro g...

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Detalles Bibliográficos
Autores principales: Gowda, B. Thimme, Foro, Sabine, Nirmala, P. G., Fuess, Hartmut
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977482/
https://www.ncbi.nlm.nih.gov/pubmed/21583652
http://dx.doi.org/10.1107/S1600536809028840
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author Gowda, B. Thimme
Foro, Sabine
Nirmala, P. G.
Fuess, Hartmut
author_facet Gowda, B. Thimme
Foro, Sabine
Nirmala, P. G.
Fuess, Hartmut
author_sort Gowda, B. Thimme
collection PubMed
description In the crystal structure of the title compound, C(14)H(13)Cl(2)NO(2)S, the configurations of the N—C bond with respect to the S=O bonds are trans and gauche. The mol­ecule is bent at the S atom with a C—SO(2)—NH—C torsion angle of −69.7 (2)°. The conformation of the N—H bond is syn to the 3-chloro group in the substituted aniline ring. The two benzene rings are tilted with respect to each other by 82.4 (1)°. The presence of N—H⋯O(S) hydrogen bonding packs the mol­ecules into supra­molecular chains along the b axis.
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spelling pubmed-29774822010-12-30 N-(3,4-Dichloro­phen­yl)-2,4-dimethyl­benzene­sulfonamide Gowda, B. Thimme Foro, Sabine Nirmala, P. G. Fuess, Hartmut Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal structure of the title compound, C(14)H(13)Cl(2)NO(2)S, the configurations of the N—C bond with respect to the S=O bonds are trans and gauche. The mol­ecule is bent at the S atom with a C—SO(2)—NH—C torsion angle of −69.7 (2)°. The conformation of the N—H bond is syn to the 3-chloro group in the substituted aniline ring. The two benzene rings are tilted with respect to each other by 82.4 (1)°. The presence of N—H⋯O(S) hydrogen bonding packs the mol­ecules into supra­molecular chains along the b axis. International Union of Crystallography 2009-07-25 /pmc/articles/PMC2977482/ /pubmed/21583652 http://dx.doi.org/10.1107/S1600536809028840 Text en © Gowda et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Gowda, B. Thimme
Foro, Sabine
Nirmala, P. G.
Fuess, Hartmut
N-(3,4-Dichloro­phen­yl)-2,4-dimethyl­benzene­sulfonamide
title N-(3,4-Dichloro­phen­yl)-2,4-dimethyl­benzene­sulfonamide
title_full N-(3,4-Dichloro­phen­yl)-2,4-dimethyl­benzene­sulfonamide
title_fullStr N-(3,4-Dichloro­phen­yl)-2,4-dimethyl­benzene­sulfonamide
title_full_unstemmed N-(3,4-Dichloro­phen­yl)-2,4-dimethyl­benzene­sulfonamide
title_short N-(3,4-Dichloro­phen­yl)-2,4-dimethyl­benzene­sulfonamide
title_sort n-(3,4-dichloro­phen­yl)-2,4-dimethyl­benzene­sulfonamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977482/
https://www.ncbi.nlm.nih.gov/pubmed/21583652
http://dx.doi.org/10.1107/S1600536809028840
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AT fuesshartmut n34dichlorophenyl24dimethylbenzenesulfonamide

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