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2-[(E)-2-(4-Chlorophenyl)ethenyl]-1-methylpyridinium 4-bromobenzenesulfonate
In the title compound, C(14)H(13)ClN(+)·C(6)H(4)BrO(3)S(−), the cation exists in an E configuration with respect to the ethenyl bond and is almost planar, the dihedral angle between the pyridinium and the benzene rings being 2.80 (7)°. The dihedral angles between the benzene ring of the anion and th...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977483/ https://www.ncbi.nlm.nih.gov/pubmed/21583577 http://dx.doi.org/10.1107/S1600536809026968 |
Sumario: | In the title compound, C(14)H(13)ClN(+)·C(6)H(4)BrO(3)S(−), the cation exists in an E configuration with respect to the ethenyl bond and is almost planar, the dihedral angle between the pyridinium and the benzene rings being 2.80 (7)°. The dihedral angles between the benzene ring of the anion and the pyridinium and benzene rings of the cation are 80.88 (7) and 79.05 (7)°, respectively. In the crystal, the cations are stacked into columns along the a axis as a result of π–π interactions between the pyridinium and chlorobenzene rings with a Cg⋯Cg distance of 3.6976 (8) Å. The anions are linked into chains along the a axis by weak C—H⋯O interactions. These anion chains are linked to adjacent cations by additional weak C—H⋯O and C—H⋯Br interactions, forming a two-dimensional network parallel to the ab plane. There are also short O⋯Br [3.2567 (11) Å] and C⋯O [2.9917 (18) Å] contacts. The crystal structure is further stabilized by C—H⋯π interactions involving the aromatic ring of the anion. |
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