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2-[(E)-2-(4-Chloro­phen­yl)ethen­yl]-1-methyl­pyridinium 4-bromo­benzene­sulfonate

In the title compound, C(14)H(13)ClN(+)·C(6)H(4)BrO(3)S(−), the cation exists in an E configuration with respect to the ethenyl bond and is almost planar, the dihedral angle between the pyridinium and the benzene rings being 2.80 (7)°. The dihedral angles between the benzene ring of the anion and th...

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Autores principales: Chantrapromma, Suchada, Chanawanno, Kullapa, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977483/
https://www.ncbi.nlm.nih.gov/pubmed/21583577
http://dx.doi.org/10.1107/S1600536809026968
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author Chantrapromma, Suchada
Chanawanno, Kullapa
Fun, Hoong-Kun
author_facet Chantrapromma, Suchada
Chanawanno, Kullapa
Fun, Hoong-Kun
author_sort Chantrapromma, Suchada
collection PubMed
description In the title compound, C(14)H(13)ClN(+)·C(6)H(4)BrO(3)S(−), the cation exists in an E configuration with respect to the ethenyl bond and is almost planar, the dihedral angle between the pyridinium and the benzene rings being 2.80 (7)°. The dihedral angles between the benzene ring of the anion and the pyridinium and benzene rings of the cation are 80.88 (7) and 79.05 (7)°, respectively. In the crystal, the cations are stacked into columns along the a axis as a result of π–π inter­actions between the pyridinium and chloro­benzene rings with a Cg⋯Cg distance of 3.6976 (8) Å. The anions are linked into chains along the a axis by weak C—H⋯O inter­actions. These anion chains are linked to adjacent cations by additional weak C—H⋯O and C—H⋯Br inter­actions, forming a two-dimensional network parallel to the ab plane. There are also short O⋯Br [3.2567 (11) Å] and C⋯O [2.9917 (18) Å] contacts. The crystal structure is further stabilized by C—H⋯π inter­actions involving the aromatic ring of the anion.
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spelling pubmed-29774832010-12-30 2-[(E)-2-(4-Chloro­phen­yl)ethen­yl]-1-methyl­pyridinium 4-bromo­benzene­sulfonate Chantrapromma, Suchada Chanawanno, Kullapa Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(14)H(13)ClN(+)·C(6)H(4)BrO(3)S(−), the cation exists in an E configuration with respect to the ethenyl bond and is almost planar, the dihedral angle between the pyridinium and the benzene rings being 2.80 (7)°. The dihedral angles between the benzene ring of the anion and the pyridinium and benzene rings of the cation are 80.88 (7) and 79.05 (7)°, respectively. In the crystal, the cations are stacked into columns along the a axis as a result of π–π inter­actions between the pyridinium and chloro­benzene rings with a Cg⋯Cg distance of 3.6976 (8) Å. The anions are linked into chains along the a axis by weak C—H⋯O inter­actions. These anion chains are linked to adjacent cations by additional weak C—H⋯O and C—H⋯Br inter­actions, forming a two-dimensional network parallel to the ab plane. There are also short O⋯Br [3.2567 (11) Å] and C⋯O [2.9917 (18) Å] contacts. The crystal structure is further stabilized by C—H⋯π inter­actions involving the aromatic ring of the anion. International Union of Crystallography 2009-07-18 /pmc/articles/PMC2977483/ /pubmed/21583577 http://dx.doi.org/10.1107/S1600536809026968 Text en © Chantrapromma et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Chantrapromma, Suchada
Chanawanno, Kullapa
Fun, Hoong-Kun
2-[(E)-2-(4-Chloro­phen­yl)ethen­yl]-1-methyl­pyridinium 4-bromo­benzene­sulfonate
title 2-[(E)-2-(4-Chloro­phen­yl)ethen­yl]-1-methyl­pyridinium 4-bromo­benzene­sulfonate
title_full 2-[(E)-2-(4-Chloro­phen­yl)ethen­yl]-1-methyl­pyridinium 4-bromo­benzene­sulfonate
title_fullStr 2-[(E)-2-(4-Chloro­phen­yl)ethen­yl]-1-methyl­pyridinium 4-bromo­benzene­sulfonate
title_full_unstemmed 2-[(E)-2-(4-Chloro­phen­yl)ethen­yl]-1-methyl­pyridinium 4-bromo­benzene­sulfonate
title_short 2-[(E)-2-(4-Chloro­phen­yl)ethen­yl]-1-methyl­pyridinium 4-bromo­benzene­sulfonate
title_sort 2-[(e)-2-(4-chloro­phen­yl)ethen­yl]-1-methyl­pyridinium 4-bromo­benzene­sulfonate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977483/
https://www.ncbi.nlm.nih.gov/pubmed/21583577
http://dx.doi.org/10.1107/S1600536809026968
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AT funhoongkun 2e24chlorophenylethenyl1methylpyridinium4bromobenzenesulfonate