Bis(acetone 4-phenyl­thio­semi­carbazonato-κ(2) N (1),S)zinc(II)

The Zn(II) atom in the title compound, [Zn(C(10)H(12)N(3)S)(2)], is N,S-chelated by the deprotonated Schiff base in a tetra­hedral environment. The metal atom lies on a twofold rotation axis that relates one anion to the other. The amino H atom forms an intermolecular N—H⋯π inter­action to an aromat...

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Detalles Bibliográficos
Autores principales: Tan, Kong Wai, Ng, Chew Hee, Maah, Mohd Jamil, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977486/
https://www.ncbi.nlm.nih.gov/pubmed/21583413
http://dx.doi.org/10.1107/S1600536809028244
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author Tan, Kong Wai
Ng, Chew Hee
Maah, Mohd Jamil
Ng, Seik Weng
author_facet Tan, Kong Wai
Ng, Chew Hee
Maah, Mohd Jamil
Ng, Seik Weng
author_sort Tan, Kong Wai
collection PubMed
description The Zn(II) atom in the title compound, [Zn(C(10)H(12)N(3)S)(2)], is N,S-chelated by the deprotonated Schiff base in a tetra­hedral environment. The metal atom lies on a twofold rotation axis that relates one anion to the other. The amino H atom forms an intermolecular N—H⋯π inter­action to an aromatic ring.
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spelling pubmed-29774862010-12-30 Bis(acetone 4-phenyl­thio­semi­carbazonato-κ(2) N (1),S)zinc(II) Tan, Kong Wai Ng, Chew Hee Maah, Mohd Jamil Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Zn(II) atom in the title compound, [Zn(C(10)H(12)N(3)S)(2)], is N,S-chelated by the deprotonated Schiff base in a tetra­hedral environment. The metal atom lies on a twofold rotation axis that relates one anion to the other. The amino H atom forms an intermolecular N—H⋯π inter­action to an aromatic ring. International Union of Crystallography 2009-07-22 /pmc/articles/PMC2977486/ /pubmed/21583413 http://dx.doi.org/10.1107/S1600536809028244 Text en © Tan et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Tan, Kong Wai
Ng, Chew Hee
Maah, Mohd Jamil
Ng, Seik Weng
Bis(acetone 4-phenyl­thio­semi­carbazonato-κ(2) N (1),S)zinc(II)
title Bis(acetone 4-phenyl­thio­semi­carbazonato-κ(2) N (1),S)zinc(II)
title_full Bis(acetone 4-phenyl­thio­semi­carbazonato-κ(2) N (1),S)zinc(II)
title_fullStr Bis(acetone 4-phenyl­thio­semi­carbazonato-κ(2) N (1),S)zinc(II)
title_full_unstemmed Bis(acetone 4-phenyl­thio­semi­carbazonato-κ(2) N (1),S)zinc(II)
title_short Bis(acetone 4-phenyl­thio­semi­carbazonato-κ(2) N (1),S)zinc(II)
title_sort bis(acetone 4-phenyl­thio­semi­carbazonato-κ(2) n (1),s)zinc(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977486/
https://www.ncbi.nlm.nih.gov/pubmed/21583413
http://dx.doi.org/10.1107/S1600536809028244
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AT ngchewhee bisacetone4phenylthiosemicarbazonatok2n1szincii
AT maahmohdjamil bisacetone4phenylthiosemicarbazonatok2n1szincii
AT ngseikweng bisacetone4phenylthiosemicarbazonatok2n1szincii

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