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Bis(μ-4-nitrophthalato)bis[diaqua(1,10-phenanthroline)manganese(II)]
In the title compound, [Mn(2)(C(8)H(3)NO(6))(2)(C(12)H(8)N(2))(2)(H(2)O)(4)], the Mn(II) atom in the centrosymmetric binuclear unit has a distorted octahedral geometry and is coordinated by a chelating 1,10-phenanthroline ligand, two monodentate carboxylate anions from two 4-nitrophthalates and t...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977488/ https://www.ncbi.nlm.nih.gov/pubmed/21583325 http://dx.doi.org/10.1107/S1600536809024064 |
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author | Xu, Bi-Yi Xie, Ting Lu, Sheng-Jun Xue, Bin Li, Wei |
author_facet | Xu, Bi-Yi Xie, Ting Lu, Sheng-Jun Xue, Bin Li, Wei |
author_sort | Xu, Bi-Yi |
collection | PubMed |
description | In the title compound, [Mn(2)(C(8)H(3)NO(6))(2)(C(12)H(8)N(2))(2)(H(2)O)(4)], the Mn(II) atom in the centrosymmetric binuclear unit has a distorted octahedral geometry and is coordinated by a chelating 1,10-phenanthroline ligand, two monodentate carboxylate anions from two 4-nitrophthalates and two coordinated water molecules. The two Mn(II) ions in the molecule are bridged by two 4-nitrophthalate anions, both in a bis-monodentate mode, which finally leads to the formation of the binuclear unit. Intramolecular O—H⋯O hydrogen bonds between the coordinated and uncoordinated O atoms of one monodentate carboxylate group and the corresponding coordinated water molecules result in an eight-membered and two six-membered rings. In the crystal structure, intermolecular O—H⋯O hydrogen bonds link the dinuclear molecules into supramolecular chains propagating parallel to [100]. |
format | Text |
id | pubmed-2977488 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29774882010-12-30 Bis(μ-4-nitrophthalato)bis[diaqua(1,10-phenanthroline)manganese(II)] Xu, Bi-Yi Xie, Ting Lu, Sheng-Jun Xue, Bin Li, Wei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Mn(2)(C(8)H(3)NO(6))(2)(C(12)H(8)N(2))(2)(H(2)O)(4)], the Mn(II) atom in the centrosymmetric binuclear unit has a distorted octahedral geometry and is coordinated by a chelating 1,10-phenanthroline ligand, two monodentate carboxylate anions from two 4-nitrophthalates and two coordinated water molecules. The two Mn(II) ions in the molecule are bridged by two 4-nitrophthalate anions, both in a bis-monodentate mode, which finally leads to the formation of the binuclear unit. Intramolecular O—H⋯O hydrogen bonds between the coordinated and uncoordinated O atoms of one monodentate carboxylate group and the corresponding coordinated water molecules result in an eight-membered and two six-membered rings. In the crystal structure, intermolecular O—H⋯O hydrogen bonds link the dinuclear molecules into supramolecular chains propagating parallel to [100]. International Union of Crystallography 2009-07-01 /pmc/articles/PMC2977488/ /pubmed/21583325 http://dx.doi.org/10.1107/S1600536809024064 Text en © Xu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Xu, Bi-Yi Xie, Ting Lu, Sheng-Jun Xue, Bin Li, Wei Bis(μ-4-nitrophthalato)bis[diaqua(1,10-phenanthroline)manganese(II)] |
title | Bis(μ-4-nitrophthalato)bis[diaqua(1,10-phenanthroline)manganese(II)] |
title_full | Bis(μ-4-nitrophthalato)bis[diaqua(1,10-phenanthroline)manganese(II)] |
title_fullStr | Bis(μ-4-nitrophthalato)bis[diaqua(1,10-phenanthroline)manganese(II)] |
title_full_unstemmed | Bis(μ-4-nitrophthalato)bis[diaqua(1,10-phenanthroline)manganese(II)] |
title_short | Bis(μ-4-nitrophthalato)bis[diaqua(1,10-phenanthroline)manganese(II)] |
title_sort | bis(μ-4-nitrophthalato)bis[diaqua(1,10-phenanthroline)manganese(ii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977488/ https://www.ncbi.nlm.nih.gov/pubmed/21583325 http://dx.doi.org/10.1107/S1600536809024064 |
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