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Bis(μ-4-nitro­phthalato)bis­[diaqua­(1,10-phenanthroline)manganese(II)]

In the title compound, [Mn(2)(C(8)H(3)NO(6))(2)(C(12)H(8)N(2))(2)(H(2)O)(4)], the Mn(II) atom in the centrosymmetric binuclear unit has a distorted octa­hedral geometry and is coordinated by a chelating 1,10-phenanthroline ligand, two monodentate carboxyl­ate anions from two 4-nitro­phthalates and t...

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Detalles Bibliográficos
Autores principales: Xu, Bi-Yi, Xie, Ting, Lu, Sheng-Jun, Xue, Bin, Li, Wei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977488/
https://www.ncbi.nlm.nih.gov/pubmed/21583325
http://dx.doi.org/10.1107/S1600536809024064
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author Xu, Bi-Yi
Xie, Ting
Lu, Sheng-Jun
Xue, Bin
Li, Wei
author_facet Xu, Bi-Yi
Xie, Ting
Lu, Sheng-Jun
Xue, Bin
Li, Wei
author_sort Xu, Bi-Yi
collection PubMed
description In the title compound, [Mn(2)(C(8)H(3)NO(6))(2)(C(12)H(8)N(2))(2)(H(2)O)(4)], the Mn(II) atom in the centrosymmetric binuclear unit has a distorted octa­hedral geometry and is coordinated by a chelating 1,10-phenanthroline ligand, two monodentate carboxyl­ate anions from two 4-nitro­phthalates and two coordinated water mol­ecules. The two Mn(II) ions in the mol­ecule are bridged by two 4-nitro­phthalate anions, both in a bis-monodentate mode, which finally leads to the formation of the binuclear unit. Intra­molecular O—H⋯O hydrogen bonds between the coordinated and uncoordinated O atoms of one monodentate carboxyl­ate group and the corresponding coordinated water mol­ecules result in an eight-membered and two six-membered rings. In the crystal structure, inter­molecular O—H⋯O hydrogen bonds link the dinuclear mol­ecules into supra­molecular chains propagating parallel to [100].
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spelling pubmed-29774882010-12-30 Bis(μ-4-nitro­phthalato)bis­[diaqua­(1,10-phenanthroline)manganese(II)] Xu, Bi-Yi Xie, Ting Lu, Sheng-Jun Xue, Bin Li, Wei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Mn(2)(C(8)H(3)NO(6))(2)(C(12)H(8)N(2))(2)(H(2)O)(4)], the Mn(II) atom in the centrosymmetric binuclear unit has a distorted octa­hedral geometry and is coordinated by a chelating 1,10-phenanthroline ligand, two monodentate carboxyl­ate anions from two 4-nitro­phthalates and two coordinated water mol­ecules. The two Mn(II) ions in the mol­ecule are bridged by two 4-nitro­phthalate anions, both in a bis-monodentate mode, which finally leads to the formation of the binuclear unit. Intra­molecular O—H⋯O hydrogen bonds between the coordinated and uncoordinated O atoms of one monodentate carboxyl­ate group and the corresponding coordinated water mol­ecules result in an eight-membered and two six-membered rings. In the crystal structure, inter­molecular O—H⋯O hydrogen bonds link the dinuclear mol­ecules into supra­molecular chains propagating parallel to [100]. International Union of Crystallography 2009-07-01 /pmc/articles/PMC2977488/ /pubmed/21583325 http://dx.doi.org/10.1107/S1600536809024064 Text en © Xu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Xu, Bi-Yi
Xie, Ting
Lu, Sheng-Jun
Xue, Bin
Li, Wei
Bis(μ-4-nitro­phthalato)bis­[diaqua­(1,10-phenanthroline)manganese(II)]
title Bis(μ-4-nitro­phthalato)bis­[diaqua­(1,10-phenanthroline)manganese(II)]
title_full Bis(μ-4-nitro­phthalato)bis­[diaqua­(1,10-phenanthroline)manganese(II)]
title_fullStr Bis(μ-4-nitro­phthalato)bis­[diaqua­(1,10-phenanthroline)manganese(II)]
title_full_unstemmed Bis(μ-4-nitro­phthalato)bis­[diaqua­(1,10-phenanthroline)manganese(II)]
title_short Bis(μ-4-nitro­phthalato)bis­[diaqua­(1,10-phenanthroline)manganese(II)]
title_sort bis(μ-4-nitro­phthalato)bis­[diaqua­(1,10-phenanthroline)manganese(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977488/
https://www.ncbi.nlm.nih.gov/pubmed/21583325
http://dx.doi.org/10.1107/S1600536809024064
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