Cargando…
Tris{2-[4-(2-pyridyl)pyrimidin-2-ylsulfanyl]ethyl}amine
The tripodal character of the title compound, C(33)H(30)N(10)S(3), arises from the three thioether arms surrounding a central amine N atom. The three arms have approximately the same conformation but distinct geometries in a trans–trans–cis conformation, resulting in a short pyridine–sulfanyl N⋯S d...
Autores principales: | , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977494/ https://www.ncbi.nlm.nih.gov/pubmed/21583580 http://dx.doi.org/10.1107/S160053680902741X |
Sumario: | The tripodal character of the title compound, C(33)H(30)N(10)S(3), arises from the three thioether arms surrounding a central amine N atom. The three arms have approximately the same conformation but distinct geometries in a trans–trans–cis conformation, resulting in a short pyridine–sulfanyl N⋯S distance of 4.320 (7) Å. The distances of the central N atom to the N atoms of three pyridine rings in the arms are 8.305 (7), 8.032 (7) and 5.076 (9)Å. In the crystal, molecules are joined into a three-dimensional supramolecular network via effective π–π stacking between adjacent heterocycles [centroid–centroid distances of 3.700 (3)–4.118 (4) Å between adjacent interlayer pyrimidine rings and 3.676 (4) Å between the pyridine rings]. |
---|