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Tris{2-[4-(2-pyridyl)pyrimidin-2-ylsulfanyl]ethyl}amine
The tripodal character of the title compound, C(33)H(30)N(10)S(3), arises from the three thioether arms surrounding a central amine N atom. The three arms have approximately the same conformation but distinct geometries in a trans–trans–cis conformation, resulting in a short pyridine–sulfanyl N⋯S d...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977494/ https://www.ncbi.nlm.nih.gov/pubmed/21583580 http://dx.doi.org/10.1107/S160053680902741X |
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author | Wang, Jian-Quan Zhang, Ya-Wen Cheng, Lin |
author_facet | Wang, Jian-Quan Zhang, Ya-Wen Cheng, Lin |
author_sort | Wang, Jian-Quan |
collection | PubMed |
description | The tripodal character of the title compound, C(33)H(30)N(10)S(3), arises from the three thioether arms surrounding a central amine N atom. The three arms have approximately the same conformation but distinct geometries in a trans–trans–cis conformation, resulting in a short pyridine–sulfanyl N⋯S distance of 4.320 (7) Å. The distances of the central N atom to the N atoms of three pyridine rings in the arms are 8.305 (7), 8.032 (7) and 5.076 (9)Å. In the crystal, molecules are joined into a three-dimensional supramolecular network via effective π–π stacking between adjacent heterocycles [centroid–centroid distances of 3.700 (3)–4.118 (4) Å between adjacent interlayer pyrimidine rings and 3.676 (4) Å between the pyridine rings]. |
format | Text |
id | pubmed-2977494 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29774942010-12-30 Tris{2-[4-(2-pyridyl)pyrimidin-2-ylsulfanyl]ethyl}amine Wang, Jian-Quan Zhang, Ya-Wen Cheng, Lin Acta Crystallogr Sect E Struct Rep Online Organic Papers The tripodal character of the title compound, C(33)H(30)N(10)S(3), arises from the three thioether arms surrounding a central amine N atom. The three arms have approximately the same conformation but distinct geometries in a trans–trans–cis conformation, resulting in a short pyridine–sulfanyl N⋯S distance of 4.320 (7) Å. The distances of the central N atom to the N atoms of three pyridine rings in the arms are 8.305 (7), 8.032 (7) and 5.076 (9)Å. In the crystal, molecules are joined into a three-dimensional supramolecular network via effective π–π stacking between adjacent heterocycles [centroid–centroid distances of 3.700 (3)–4.118 (4) Å between adjacent interlayer pyrimidine rings and 3.676 (4) Å between the pyridine rings]. International Union of Crystallography 2009-07-18 /pmc/articles/PMC2977494/ /pubmed/21583580 http://dx.doi.org/10.1107/S160053680902741X Text en © Wang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Wang, Jian-Quan Zhang, Ya-Wen Cheng, Lin Tris{2-[4-(2-pyridyl)pyrimidin-2-ylsulfanyl]ethyl}amine |
title | Tris{2-[4-(2-pyridyl)pyrimidin-2-ylsulfanyl]ethyl}amine |
title_full | Tris{2-[4-(2-pyridyl)pyrimidin-2-ylsulfanyl]ethyl}amine |
title_fullStr | Tris{2-[4-(2-pyridyl)pyrimidin-2-ylsulfanyl]ethyl}amine |
title_full_unstemmed | Tris{2-[4-(2-pyridyl)pyrimidin-2-ylsulfanyl]ethyl}amine |
title_short | Tris{2-[4-(2-pyridyl)pyrimidin-2-ylsulfanyl]ethyl}amine |
title_sort | tris{2-[4-(2-pyridyl)pyrimidin-2-ylsulfanyl]ethyl}amine |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977494/ https://www.ncbi.nlm.nih.gov/pubmed/21583580 http://dx.doi.org/10.1107/S160053680902741X |
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