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Tris{2-[4-(2-pyrid­yl)pyrimidin-2-ylsulfan­yl]eth­yl}amine

The tripodal character of the title compound, C(33)H(30)N(10)S(3), arises from the three thio­ether arms surrounding a central amine N atom. The three arms have approximately the same conformation but distinct geometries in a trans–trans–cis conformation, resulting in a short pyridine–sulfanyl N⋯S d...

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Detalles Bibliográficos
Autores principales: Wang, Jian-Quan, Zhang, Ya-Wen, Cheng, Lin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977494/
https://www.ncbi.nlm.nih.gov/pubmed/21583580
http://dx.doi.org/10.1107/S160053680902741X
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author Wang, Jian-Quan
Zhang, Ya-Wen
Cheng, Lin
author_facet Wang, Jian-Quan
Zhang, Ya-Wen
Cheng, Lin
author_sort Wang, Jian-Quan
collection PubMed
description The tripodal character of the title compound, C(33)H(30)N(10)S(3), arises from the three thio­ether arms surrounding a central amine N atom. The three arms have approximately the same conformation but distinct geometries in a trans–trans–cis conformation, resulting in a short pyridine–sulfanyl N⋯S distance of 4.320 (7) Å. The distances of the central N atom to the N atoms of three pyridine rings in the arms are 8.305 (7), 8.032 (7) and 5.076 (9)Å. In the crystal, mol­ecules are joined into a three-dimensional supra­molecular network via effective π–π stacking between adjacent heterocycles [centroid–centroid distances of 3.700 (3)–4.118 (4) Å between adjacent inter­layer pyrimidine rings and 3.676 (4) Å between the pyridine rings].
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spelling pubmed-29774942010-12-30 Tris{2-[4-(2-pyrid­yl)pyrimidin-2-ylsulfan­yl]eth­yl}amine Wang, Jian-Quan Zhang, Ya-Wen Cheng, Lin Acta Crystallogr Sect E Struct Rep Online Organic Papers The tripodal character of the title compound, C(33)H(30)N(10)S(3), arises from the three thio­ether arms surrounding a central amine N atom. The three arms have approximately the same conformation but distinct geometries in a trans–trans–cis conformation, resulting in a short pyridine–sulfanyl N⋯S distance of 4.320 (7) Å. The distances of the central N atom to the N atoms of three pyridine rings in the arms are 8.305 (7), 8.032 (7) and 5.076 (9)Å. In the crystal, mol­ecules are joined into a three-dimensional supra­molecular network via effective π–π stacking between adjacent heterocycles [centroid–centroid distances of 3.700 (3)–4.118 (4) Å between adjacent inter­layer pyrimidine rings and 3.676 (4) Å between the pyridine rings]. International Union of Crystallography 2009-07-18 /pmc/articles/PMC2977494/ /pubmed/21583580 http://dx.doi.org/10.1107/S160053680902741X Text en © Wang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Wang, Jian-Quan
Zhang, Ya-Wen
Cheng, Lin
Tris{2-[4-(2-pyrid­yl)pyrimidin-2-ylsulfan­yl]eth­yl}amine
title Tris{2-[4-(2-pyrid­yl)pyrimidin-2-ylsulfan­yl]eth­yl}amine
title_full Tris{2-[4-(2-pyrid­yl)pyrimidin-2-ylsulfan­yl]eth­yl}amine
title_fullStr Tris{2-[4-(2-pyrid­yl)pyrimidin-2-ylsulfan­yl]eth­yl}amine
title_full_unstemmed Tris{2-[4-(2-pyrid­yl)pyrimidin-2-ylsulfan­yl]eth­yl}amine
title_short Tris{2-[4-(2-pyrid­yl)pyrimidin-2-ylsulfan­yl]eth­yl}amine
title_sort tris{2-[4-(2-pyrid­yl)pyrimidin-2-ylsulfan­yl]eth­yl}amine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977494/
https://www.ncbi.nlm.nih.gov/pubmed/21583580
http://dx.doi.org/10.1107/S160053680902741X
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