1,2-Bis[1-(3-methyl­sulfanyl-1,2,4-triazin-5-yl)ethyl­idene]diazane

The mol­ecule of the title compound, C(12)H(14)N(8)S(2), has an N—N gauche conformation. The triazine rings are nearly coplanar with respect to the imide bonds [C—C—C—N torsion angles = −15.3 (3) and −15.8 (3)°] and they are twisted by 77.88 (7)°. The overall conformation of the mol­ecule is stabili...

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Autores principales: Mojzych, Mariusz, Karczmarzyk, Zbigniew, Urbańczyk-Lipkowska, Zofia, Kalicki, Przemysław
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977495/
https://www.ncbi.nlm.nih.gov/pubmed/21583480
http://dx.doi.org/10.1107/S1600536809025033
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author Mojzych, Mariusz
Karczmarzyk, Zbigniew
Urbańczyk-Lipkowska, Zofia
Kalicki, Przemysław
author_facet Mojzych, Mariusz
Karczmarzyk, Zbigniew
Urbańczyk-Lipkowska, Zofia
Kalicki, Przemysław
author_sort Mojzych, Mariusz
collection PubMed
description The mol­ecule of the title compound, C(12)H(14)N(8)S(2), has an N—N gauche conformation. The triazine rings are nearly coplanar with respect to the imide bonds [C—C—C—N torsion angles = −15.3 (3) and −15.8 (3)°] and they are twisted by 77.88 (7)°. The overall conformation of the mol­ecule is stabilized by intra­molecular C—H⋯N hydrogen bonding. The mol­ecular packing is influenced by π–π inter­actions of the triazine systems with a shortest centroid–centroid separation of 3.5242 (12) Å.
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spelling pubmed-29774952010-12-30 1,2-Bis[1-(3-methyl­sulfanyl-1,2,4-triazin-5-yl)ethyl­idene]diazane Mojzych, Mariusz Karczmarzyk, Zbigniew Urbańczyk-Lipkowska, Zofia Kalicki, Przemysław Acta Crystallogr Sect E Struct Rep Online Organic Papers The mol­ecule of the title compound, C(12)H(14)N(8)S(2), has an N—N gauche conformation. The triazine rings are nearly coplanar with respect to the imide bonds [C—C—C—N torsion angles = −15.3 (3) and −15.8 (3)°] and they are twisted by 77.88 (7)°. The overall conformation of the mol­ecule is stabilized by intra­molecular C—H⋯N hydrogen bonding. The mol­ecular packing is influenced by π–π inter­actions of the triazine systems with a shortest centroid–centroid separation of 3.5242 (12) Å. International Union of Crystallography 2009-07-04 /pmc/articles/PMC2977495/ /pubmed/21583480 http://dx.doi.org/10.1107/S1600536809025033 Text en © Mojzych et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Mojzych, Mariusz
Karczmarzyk, Zbigniew
Urbańczyk-Lipkowska, Zofia
Kalicki, Przemysław
1,2-Bis[1-(3-methyl­sulfanyl-1,2,4-triazin-5-yl)ethyl­idene]diazane
title 1,2-Bis[1-(3-methyl­sulfanyl-1,2,4-triazin-5-yl)ethyl­idene]diazane
title_full 1,2-Bis[1-(3-methyl­sulfanyl-1,2,4-triazin-5-yl)ethyl­idene]diazane
title_fullStr 1,2-Bis[1-(3-methyl­sulfanyl-1,2,4-triazin-5-yl)ethyl­idene]diazane
title_full_unstemmed 1,2-Bis[1-(3-methyl­sulfanyl-1,2,4-triazin-5-yl)ethyl­idene]diazane
title_short 1,2-Bis[1-(3-methyl­sulfanyl-1,2,4-triazin-5-yl)ethyl­idene]diazane
title_sort 1,2-bis[1-(3-methyl­sulfanyl-1,2,4-triazin-5-yl)ethyl­idene]diazane
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977495/
https://www.ncbi.nlm.nih.gov/pubmed/21583480
http://dx.doi.org/10.1107/S1600536809025033
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AT karczmarzykzbigniew 12bis13methylsulfanyl124triazin5ylethylidenediazane
AT urbanczyklipkowskazofia 12bis13methylsulfanyl124triazin5ylethylidenediazane
AT kalickiprzemysław 12bis13methylsulfanyl124triazin5ylethylidenediazane

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