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Poly[μ-aqua-di-μ-benzoato-lead(II)]

The reaction of lead(II) nitrate and benzoic acid in aqueous solution yields the title polymer, [Pb(C(7)H(5)O(2))(2)(H(2)O)](n). The asymmetric unit contains one Pb(II) ion, two benzoate ligands and one water mol­ecule. The Pb—O bond distances are in the range 2.494 (4)–2.735 (4) Å. The Pb⋯Pb distan...

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Detalles Bibliográficos
Autores principales: Li, Jiantong, Yang, Juan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977498/
https://www.ncbi.nlm.nih.gov/pubmed/21583430
http://dx.doi.org/10.1107/S1600536809028542
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author Li, Jiantong
Yang, Juan
author_facet Li, Jiantong
Yang, Juan
author_sort Li, Jiantong
collection PubMed
description The reaction of lead(II) nitrate and benzoic acid in aqueous solution yields the title polymer, [Pb(C(7)H(5)O(2))(2)(H(2)O)](n). The asymmetric unit contains one Pb(II) ion, two benzoate ligands and one water mol­ecule. The Pb—O bond distances are in the range 2.494 (4)–2.735 (4) Å. The Pb⋯Pb distance is 4.0683 (4) Å, indicating an insignificant metal–metal inter­action. The Pb(II) atom has a distorted penta­gonal-bipyramidal geometry chelated by two carboxyl­ate O atoms. The Pb atoms are bridged through a coordinating water mol­ecule and two carboxyl­ate O atoms from another two benzoate ligands, giving an infinite three-dimensional supra­molecular structure. O—H⋯O hydrogen-bonding inter­actions involved the coordinating water and carboxyl­ate O atoms enhance the stability of the supra­molecular arrangement.
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spelling pubmed-29774982010-12-30 Poly[μ-aqua-di-μ-benzoato-lead(II)] Li, Jiantong Yang, Juan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The reaction of lead(II) nitrate and benzoic acid in aqueous solution yields the title polymer, [Pb(C(7)H(5)O(2))(2)(H(2)O)](n). The asymmetric unit contains one Pb(II) ion, two benzoate ligands and one water mol­ecule. The Pb—O bond distances are in the range 2.494 (4)–2.735 (4) Å. The Pb⋯Pb distance is 4.0683 (4) Å, indicating an insignificant metal–metal inter­action. The Pb(II) atom has a distorted penta­gonal-bipyramidal geometry chelated by two carboxyl­ate O atoms. The Pb atoms are bridged through a coordinating water mol­ecule and two carboxyl­ate O atoms from another two benzoate ligands, giving an infinite three-dimensional supra­molecular structure. O—H⋯O hydrogen-bonding inter­actions involved the coordinating water and carboxyl­ate O atoms enhance the stability of the supra­molecular arrangement. International Union of Crystallography 2009-07-25 /pmc/articles/PMC2977498/ /pubmed/21583430 http://dx.doi.org/10.1107/S1600536809028542 Text en © Li and Yang 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Jiantong
Yang, Juan
Poly[μ-aqua-di-μ-benzoato-lead(II)]
title Poly[μ-aqua-di-μ-benzoato-lead(II)]
title_full Poly[μ-aqua-di-μ-benzoato-lead(II)]
title_fullStr Poly[μ-aqua-di-μ-benzoato-lead(II)]
title_full_unstemmed Poly[μ-aqua-di-μ-benzoato-lead(II)]
title_short Poly[μ-aqua-di-μ-benzoato-lead(II)]
title_sort poly[μ-aqua-di-μ-benzoato-lead(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977498/
https://www.ncbi.nlm.nih.gov/pubmed/21583430
http://dx.doi.org/10.1107/S1600536809028542
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AT yangjuan polymaquadimbenzoatoleadii