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Poly[μ-aqua-di-μ-benzoato-lead(II)]
The reaction of lead(II) nitrate and benzoic acid in aqueous solution yields the title polymer, [Pb(C(7)H(5)O(2))(2)(H(2)O)](n). The asymmetric unit contains one Pb(II) ion, two benzoate ligands and one water molecule. The Pb—O bond distances are in the range 2.494 (4)–2.735 (4) Å. The Pb⋯Pb distan...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977498/ https://www.ncbi.nlm.nih.gov/pubmed/21583430 http://dx.doi.org/10.1107/S1600536809028542 |
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author | Li, Jiantong Yang, Juan |
author_facet | Li, Jiantong Yang, Juan |
author_sort | Li, Jiantong |
collection | PubMed |
description | The reaction of lead(II) nitrate and benzoic acid in aqueous solution yields the title polymer, [Pb(C(7)H(5)O(2))(2)(H(2)O)](n). The asymmetric unit contains one Pb(II) ion, two benzoate ligands and one water molecule. The Pb—O bond distances are in the range 2.494 (4)–2.735 (4) Å. The Pb⋯Pb distance is 4.0683 (4) Å, indicating an insignificant metal–metal interaction. The Pb(II) atom has a distorted pentagonal-bipyramidal geometry chelated by two carboxylate O atoms. The Pb atoms are bridged through a coordinating water molecule and two carboxylate O atoms from another two benzoate ligands, giving an infinite three-dimensional supramolecular structure. O—H⋯O hydrogen-bonding interactions involved the coordinating water and carboxylate O atoms enhance the stability of the supramolecular arrangement. |
format | Text |
id | pubmed-2977498 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29774982010-12-30 Poly[μ-aqua-di-μ-benzoato-lead(II)] Li, Jiantong Yang, Juan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The reaction of lead(II) nitrate and benzoic acid in aqueous solution yields the title polymer, [Pb(C(7)H(5)O(2))(2)(H(2)O)](n). The asymmetric unit contains one Pb(II) ion, two benzoate ligands and one water molecule. The Pb—O bond distances are in the range 2.494 (4)–2.735 (4) Å. The Pb⋯Pb distance is 4.0683 (4) Å, indicating an insignificant metal–metal interaction. The Pb(II) atom has a distorted pentagonal-bipyramidal geometry chelated by two carboxylate O atoms. The Pb atoms are bridged through a coordinating water molecule and two carboxylate O atoms from another two benzoate ligands, giving an infinite three-dimensional supramolecular structure. O—H⋯O hydrogen-bonding interactions involved the coordinating water and carboxylate O atoms enhance the stability of the supramolecular arrangement. International Union of Crystallography 2009-07-25 /pmc/articles/PMC2977498/ /pubmed/21583430 http://dx.doi.org/10.1107/S1600536809028542 Text en © Li and Yang 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Li, Jiantong Yang, Juan Poly[μ-aqua-di-μ-benzoato-lead(II)] |
title | Poly[μ-aqua-di-μ-benzoato-lead(II)] |
title_full | Poly[μ-aqua-di-μ-benzoato-lead(II)] |
title_fullStr | Poly[μ-aqua-di-μ-benzoato-lead(II)] |
title_full_unstemmed | Poly[μ-aqua-di-μ-benzoato-lead(II)] |
title_short | Poly[μ-aqua-di-μ-benzoato-lead(II)] |
title_sort | poly[μ-aqua-di-μ-benzoato-lead(ii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977498/ https://www.ncbi.nlm.nih.gov/pubmed/21583430 http://dx.doi.org/10.1107/S1600536809028542 |
work_keys_str_mv | AT lijiantong polymaquadimbenzoatoleadii AT yangjuan polymaquadimbenzoatoleadii |