catena-Poly[[[2-(2-pyrid­yl)-1H-benz­imidazole]cadmium(II)]-μ-benzene-1,4-dicarboxyl­ato]

In the title compound, [Cd(C(8)H(4)O(4))(C(12)H(9)N(3))](n), each Cd(II) ion is six-coordinated in a distorted octa­hedral geometry by four carboxyl­ate O atoms from two benzene-1,4-dicarboxyl­ate anions (L), and two N atoms from one 2-(2-pyrid­yl)benzimidazole ligand. The neighboring Cd(II) ions ar...

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Detalles Bibliográficos
Autores principales: Liu, Hai-Yan, Zhao, Da-Wei, Sun, Hong-Mei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977500/
https://www.ncbi.nlm.nih.gov/pubmed/21583375
http://dx.doi.org/10.1107/S1600536809026890
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author Liu, Hai-Yan
Zhao, Da-Wei
Sun, Hong-Mei
author_facet Liu, Hai-Yan
Zhao, Da-Wei
Sun, Hong-Mei
author_sort Liu, Hai-Yan
collection PubMed
description In the title compound, [Cd(C(8)H(4)O(4))(C(12)H(9)N(3))](n), each Cd(II) ion is six-coordinated in a distorted octa­hedral geometry by four carboxyl­ate O atoms from two benzene-1,4-dicarboxyl­ate anions (L), and two N atoms from one 2-(2-pyrid­yl)benzimidazole ligand. The neighboring Cd(II) ions are bridged by the L ligands, forming a zigzag polymeric chain structure. The chains are further extended into a three-dimensional supra­molecular structure through inter­molecular N—H⋯O hydrogen bonds.
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spelling pubmed-29775002010-12-30 catena-Poly[[[2-(2-pyrid­yl)-1H-benz­imidazole]cadmium(II)]-μ-benzene-1,4-dicarboxyl­ato] Liu, Hai-Yan Zhao, Da-Wei Sun, Hong-Mei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cd(C(8)H(4)O(4))(C(12)H(9)N(3))](n), each Cd(II) ion is six-coordinated in a distorted octa­hedral geometry by four carboxyl­ate O atoms from two benzene-1,4-dicarboxyl­ate anions (L), and two N atoms from one 2-(2-pyrid­yl)benzimidazole ligand. The neighboring Cd(II) ions are bridged by the L ligands, forming a zigzag polymeric chain structure. The chains are further extended into a three-dimensional supra­molecular structure through inter­molecular N—H⋯O hydrogen bonds. International Union of Crystallography 2009-07-15 /pmc/articles/PMC2977500/ /pubmed/21583375 http://dx.doi.org/10.1107/S1600536809026890 Text en © Liu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Hai-Yan
Zhao, Da-Wei
Sun, Hong-Mei
catena-Poly[[[2-(2-pyrid­yl)-1H-benz­imidazole]cadmium(II)]-μ-benzene-1,4-dicarboxyl­ato]
title catena-Poly[[[2-(2-pyrid­yl)-1H-benz­imidazole]cadmium(II)]-μ-benzene-1,4-dicarboxyl­ato]
title_full catena-Poly[[[2-(2-pyrid­yl)-1H-benz­imidazole]cadmium(II)]-μ-benzene-1,4-dicarboxyl­ato]
title_fullStr catena-Poly[[[2-(2-pyrid­yl)-1H-benz­imidazole]cadmium(II)]-μ-benzene-1,4-dicarboxyl­ato]
title_full_unstemmed catena-Poly[[[2-(2-pyrid­yl)-1H-benz­imidazole]cadmium(II)]-μ-benzene-1,4-dicarboxyl­ato]
title_short catena-Poly[[[2-(2-pyrid­yl)-1H-benz­imidazole]cadmium(II)]-μ-benzene-1,4-dicarboxyl­ato]
title_sort catena-poly[[[2-(2-pyrid­yl)-1h-benz­imidazole]cadmium(ii)]-μ-benzene-1,4-dicarboxyl­ato]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977500/
https://www.ncbi.nlm.nih.gov/pubmed/21583375
http://dx.doi.org/10.1107/S1600536809026890
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