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Chlorido(chlorodiphenylphosphine-κP)(diphenylpiperidinophosphine-κP)(η(5)-pentamethylcyclopentadienyl)ruthenium(II)
The title compound, [Ru(C(10)H(15))Cl(C(12)H(10)ClP)(C(17)H(20)NP)], is a half-sandwich complex of Ru(II) with the chlorodiphenylphosphine ligand formed from the diphenylpiperidinophosphine and chlorine of the precursor complex [Ru(η(5)-C(5)Me(5))(κ(1)P—Ph(2)PNC(5)H(10))Cl(2)] by an unexpected re...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
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International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977503/ https://www.ncbi.nlm.nih.gov/pubmed/21583392 http://dx.doi.org/10.1107/S1600536809027676 |
| _version_ | 1782191124072366080 |
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| author | Jantscher, Florian Kirchner, Karl Mereiter, Kurt |
| author_facet | Jantscher, Florian Kirchner, Karl Mereiter, Kurt |
| author_sort | Jantscher, Florian |
| collection | PubMed |
| description | The title compound, [Ru(C(10)H(15))Cl(C(12)H(10)ClP)(C(17)H(20)NP)], is a half-sandwich complex of Ru(II) with the chlorodiphenylphosphine ligand formed from the diphenylpiperidinophosphine and chlorine of the precursor complex [Ru(η(5)-C(5)Me(5))(κ(1)P—Ph(2)PNC(5)H(10))Cl(2)] by an unexpected reaction with NaBH(4). The complex has a three-legged piano-stool geometry, with Ru—P bond lengths of 2.2598 (5) Å for the chlorophosphine and 2.3303 (5) Å for the aminophosphine. |
| format | Text |
| id | pubmed-2977503 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29775032010-12-30 Chlorido(chlorodiphenylphosphine-κP)(diphenylpiperidinophosphine-κP)(η(5)-pentamethylcyclopentadienyl)ruthenium(II) Jantscher, Florian Kirchner, Karl Mereiter, Kurt Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Ru(C(10)H(15))Cl(C(12)H(10)ClP)(C(17)H(20)NP)], is a half-sandwich complex of Ru(II) with the chlorodiphenylphosphine ligand formed from the diphenylpiperidinophosphine and chlorine of the precursor complex [Ru(η(5)-C(5)Me(5))(κ(1)P—Ph(2)PNC(5)H(10))Cl(2)] by an unexpected reaction with NaBH(4). The complex has a three-legged piano-stool geometry, with Ru—P bond lengths of 2.2598 (5) Å for the chlorophosphine and 2.3303 (5) Å for the aminophosphine. International Union of Crystallography 2009-07-18 /pmc/articles/PMC2977503/ /pubmed/21583392 http://dx.doi.org/10.1107/S1600536809027676 Text en © Jantscher et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Jantscher, Florian Kirchner, Karl Mereiter, Kurt Chlorido(chlorodiphenylphosphine-κP)(diphenylpiperidinophosphine-κP)(η(5)-pentamethylcyclopentadienyl)ruthenium(II) |
| title | Chlorido(chlorodiphenylphosphine-κP)(diphenylpiperidinophosphine-κP)(η(5)-pentamethylcyclopentadienyl)ruthenium(II) |
| title_full | Chlorido(chlorodiphenylphosphine-κP)(diphenylpiperidinophosphine-κP)(η(5)-pentamethylcyclopentadienyl)ruthenium(II) |
| title_fullStr | Chlorido(chlorodiphenylphosphine-κP)(diphenylpiperidinophosphine-κP)(η(5)-pentamethylcyclopentadienyl)ruthenium(II) |
| title_full_unstemmed | Chlorido(chlorodiphenylphosphine-κP)(diphenylpiperidinophosphine-κP)(η(5)-pentamethylcyclopentadienyl)ruthenium(II) |
| title_short | Chlorido(chlorodiphenylphosphine-κP)(diphenylpiperidinophosphine-κP)(η(5)-pentamethylcyclopentadienyl)ruthenium(II) |
| title_sort | chlorido(chlorodiphenylphosphine-κp)(diphenylpiperidinophosphine-κp)(η(5)-pentamethylcyclopentadienyl)ruthenium(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977503/ https://www.ncbi.nlm.nih.gov/pubmed/21583392 http://dx.doi.org/10.1107/S1600536809027676 |
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