2-(Methoxy­carbon­yl)anilinium dihydrogen phosphate

The title compound, C(8)H(10)NO(2) (+)·H(2)PO(4) (−), is a derivative of the naturally occurring compound methyl­anthranilate. The asymmetric unit comprises the 2-(methoxy­carbon­yl)anilinium cation and the dihydrogen phosphate anion. In the cation, the dihedral angle between the benzene ring plane...

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Autores principales: Shafiq, Muhammad, Khan, Islam Ullah, Arshad, Muhammad Nadeem, Khan, Muneeb Hayat, Simpson, Jim
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977506/
https://www.ncbi.nlm.nih.gov/pubmed/21583492
http://dx.doi.org/10.1107/S1600536809025252
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author Shafiq, Muhammad
Khan, Islam Ullah
Arshad, Muhammad Nadeem
Khan, Muneeb Hayat
Simpson, Jim
author_facet Shafiq, Muhammad
Khan, Islam Ullah
Arshad, Muhammad Nadeem
Khan, Muneeb Hayat
Simpson, Jim
author_sort Shafiq, Muhammad
collection PubMed
description The title compound, C(8)H(10)NO(2) (+)·H(2)PO(4) (−), is a derivative of the naturally occurring compound methyl­anthranilate. The asymmetric unit comprises the 2-(methoxy­carbon­yl)anilinium cation and the dihydrogen phosphate anion. In the cation, the dihedral angle between the benzene ring plane and that through the methyl ester substituent is 22.94 (9)°. In the crystal, adjacent cations and anions form dimers through N—H⋯O and O—H⋯O hydrogen bonds, respectively. Additional N—H⋯O and C—H⋯O contacts result in a network of cation and anion dimers stacked down the b axis.
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spelling pubmed-29775062010-12-30 2-(Methoxy­carbon­yl)anilinium dihydrogen phosphate Shafiq, Muhammad Khan, Islam Ullah Arshad, Muhammad Nadeem Khan, Muneeb Hayat Simpson, Jim Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(8)H(10)NO(2) (+)·H(2)PO(4) (−), is a derivative of the naturally occurring compound methyl­anthranilate. The asymmetric unit comprises the 2-(methoxy­carbon­yl)anilinium cation and the dihydrogen phosphate anion. In the cation, the dihedral angle between the benzene ring plane and that through the methyl ester substituent is 22.94 (9)°. In the crystal, adjacent cations and anions form dimers through N—H⋯O and O—H⋯O hydrogen bonds, respectively. Additional N—H⋯O and C—H⋯O contacts result in a network of cation and anion dimers stacked down the b axis. International Union of Crystallography 2009-07-04 /pmc/articles/PMC2977506/ /pubmed/21583492 http://dx.doi.org/10.1107/S1600536809025252 Text en © Shafiq et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Shafiq, Muhammad
Khan, Islam Ullah
Arshad, Muhammad Nadeem
Khan, Muneeb Hayat
Simpson, Jim
2-(Methoxy­carbon­yl)anilinium dihydrogen phosphate
title 2-(Methoxy­carbon­yl)anilinium dihydrogen phosphate
title_full 2-(Methoxy­carbon­yl)anilinium dihydrogen phosphate
title_fullStr 2-(Methoxy­carbon­yl)anilinium dihydrogen phosphate
title_full_unstemmed 2-(Methoxy­carbon­yl)anilinium dihydrogen phosphate
title_short 2-(Methoxy­carbon­yl)anilinium dihydrogen phosphate
title_sort 2-(methoxy­carbon­yl)anilinium dihydrogen phosphate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977506/
https://www.ncbi.nlm.nih.gov/pubmed/21583492
http://dx.doi.org/10.1107/S1600536809025252
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AT arshadmuhammadnadeem 2methoxycarbonylaniliniumdihydrogenphosphate
AT khanmuneebhayat 2methoxycarbonylaniliniumdihydrogenphosphate
AT simpsonjim 2methoxycarbonylaniliniumdihydrogenphosphate

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