3,4,5-Trimeth­oxy-N-(2-methoxy­phen­yl)benzamide

In the title mol­ecule, C(17)H(19)NO(5), the amide plane is oriented at an angle of 41.5 (3)° with respect to the 2-methoxy­benzene ring. The three meth­oxy groups lie almost in the plane of the aromatic rings to which they are attached [C—O—C—C torsion angles of of 0.7 (4), −13.4 (4) and 3.1 (4)°],...

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Detalles Bibliográficos
Autores principales: Saeed, Aamer, Flörke, Ulrich
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977507/
https://www.ncbi.nlm.nih.gov/pubmed/21583628
http://dx.doi.org/10.1107/S1600536809027974
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author Saeed, Aamer
Flörke, Ulrich
author_facet Saeed, Aamer
Flörke, Ulrich
author_sort Saeed, Aamer
collection PubMed
description In the title mol­ecule, C(17)H(19)NO(5), the amide plane is oriented at an angle of 41.5 (3)° with respect to the 2-methoxy­benzene ring. The three meth­oxy groups lie almost in the plane of the aromatic rings to which they are attached [C—O—C—C torsion angles of of 0.7 (4), −13.4 (4) and 3.1 (4)°], whereas the meth­oxy group at the 4-position of the 3,4,5-trimethoxy­benzene ring is nearly perpendicularly oriented [C—O—C—C torsion angle of 103.9 (3)°]. In the crystal structure, inter­molecular N—H⋯O hydrogen bonds link the mol­ecules into chains along [001].
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spelling pubmed-29775072010-12-30 3,4,5-Trimeth­oxy-N-(2-methoxy­phen­yl)benzamide Saeed, Aamer Flörke, Ulrich Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecule, C(17)H(19)NO(5), the amide plane is oriented at an angle of 41.5 (3)° with respect to the 2-methoxy­benzene ring. The three meth­oxy groups lie almost in the plane of the aromatic rings to which they are attached [C—O—C—C torsion angles of of 0.7 (4), −13.4 (4) and 3.1 (4)°], whereas the meth­oxy group at the 4-position of the 3,4,5-trimethoxy­benzene ring is nearly perpendicularly oriented [C—O—C—C torsion angle of 103.9 (3)°]. In the crystal structure, inter­molecular N—H⋯O hydrogen bonds link the mol­ecules into chains along [001]. International Union of Crystallography 2009-07-22 /pmc/articles/PMC2977507/ /pubmed/21583628 http://dx.doi.org/10.1107/S1600536809027974 Text en © Saeed and Flörke 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Saeed, Aamer
Flörke, Ulrich
3,4,5-Trimeth­oxy-N-(2-methoxy­phen­yl)benzamide
title 3,4,5-Trimeth­oxy-N-(2-methoxy­phen­yl)benzamide
title_full 3,4,5-Trimeth­oxy-N-(2-methoxy­phen­yl)benzamide
title_fullStr 3,4,5-Trimeth­oxy-N-(2-methoxy­phen­yl)benzamide
title_full_unstemmed 3,4,5-Trimeth­oxy-N-(2-methoxy­phen­yl)benzamide
title_short 3,4,5-Trimeth­oxy-N-(2-methoxy­phen­yl)benzamide
title_sort 3,4,5-trimeth­oxy-n-(2-methoxy­phen­yl)benzamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977507/
https://www.ncbi.nlm.nih.gov/pubmed/21583628
http://dx.doi.org/10.1107/S1600536809027974
work_keys_str_mv AT saeedaamer 345trimethoxyn2methoxyphenylbenzamide
AT florkeulrich 345trimethoxyn2methoxyphenylbenzamide

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