The Chevrel phase HgMo(6)S(8)

The crystal structure of HgMo(6)S(8), mercury(II) hexa­molybdenum octa­sulfide, is based on (Mo(6)S(8))S(6) cluster units ([Image: see text] symmetry) inter­connected through inter­unit Mo—S bonds. The Hg(2+) cations occupy large voids between the different cluster units and are covalently bonded to...

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Detalles Bibliográficos
Autores principales: Salloum, Diala, Gougeon, Patrick, Potel, Michel
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977540/
https://www.ncbi.nlm.nih.gov/pubmed/21583726
http://dx.doi.org/10.1107/S1600536809012495
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author Salloum, Diala
Gougeon, Patrick
Potel, Michel
author_facet Salloum, Diala
Gougeon, Patrick
Potel, Michel
author_sort Salloum, Diala
collection PubMed
description The crystal structure of HgMo(6)S(8), mercury(II) hexa­molybdenum octa­sulfide, is based on (Mo(6)S(8))S(6) cluster units ([Image: see text] symmetry) inter­connected through inter­unit Mo—S bonds. The Hg(2+) cations occupy large voids between the different cluster units and are covalently bonded to two S atoms. The Hg atoms and one S atom lie on sites with crystallographic [Image: see text] and 3 symmetry, respectively. Refinement of the occupancy factor of the Hg atom led to the composition Hg(0.973 (3))Mo(6)S(8).
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spelling pubmed-29775402010-12-30 The Chevrel phase HgMo(6)S(8) Salloum, Diala Gougeon, Patrick Potel, Michel Acta Crystallogr Sect E Struct Rep Online Inorganic Papers The crystal structure of HgMo(6)S(8), mercury(II) hexa­molybdenum octa­sulfide, is based on (Mo(6)S(8))S(6) cluster units ([Image: see text] symmetry) inter­connected through inter­unit Mo—S bonds. The Hg(2+) cations occupy large voids between the different cluster units and are covalently bonded to two S atoms. The Hg atoms and one S atom lie on sites with crystallographic [Image: see text] and 3 symmetry, respectively. Refinement of the occupancy factor of the Hg atom led to the composition Hg(0.973 (3))Mo(6)S(8). International Union of Crystallography 2009-04-18 /pmc/articles/PMC2977540/ /pubmed/21583726 http://dx.doi.org/10.1107/S1600536809012495 Text en © Salloum et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Inorganic Papers
Salloum, Diala
Gougeon, Patrick
Potel, Michel
The Chevrel phase HgMo(6)S(8)
title The Chevrel phase HgMo(6)S(8)
title_full The Chevrel phase HgMo(6)S(8)
title_fullStr The Chevrel phase HgMo(6)S(8)
title_full_unstemmed The Chevrel phase HgMo(6)S(8)
title_short The Chevrel phase HgMo(6)S(8)
title_sort chevrel phase hgmo(6)s(8)
topic Inorganic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977540/
https://www.ncbi.nlm.nih.gov/pubmed/21583726
http://dx.doi.org/10.1107/S1600536809012495
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