An open-framework borophosphate, LiCu(2)BP(2)O(8)(OH)(2)

The open-framework alkaline-earth metal borophosphate, lithium dicopper(II) borophosphate dihydroxide, LiCu(2)BP(2)O(8)(OH)(2), was synthesized hydro­thermally. Its structure may be regarded as a layer formed via BO(4) and PO(4) tetra­hedra bonding together with distorted CuO(6) and LiO(6) octa­hedr...

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Detalles Bibliográficos
Autores principales: Zheng, Juan, Zhang, Aiyun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977544/
https://www.ncbi.nlm.nih.gov/pubmed/21583730
http://dx.doi.org/10.1107/S1600536809015554
Descripción
Sumario:The open-framework alkaline-earth metal borophosphate, lithium dicopper(II) borophosphate dihydroxide, LiCu(2)BP(2)O(8)(OH)(2), was synthesized hydro­thermally. Its structure may be regarded as a layer formed via BO(4) and PO(4) tetra­hedra bonding together with distorted CuO(6) and LiO(6) octa­hedral units. Each P atom is connected to B, Li and Cu atoms through a bridging O atom. The B atom lies on a crystallographic twofold axis and the Li atom lies on a center of symmetry. The two metal centers are connected to each other by Cu—O—Li bonds.

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