Tetra­aqua­bis[4-(4-pyrid­yl)pyrimidine-2-sulfonato]copper(II) dihydrate

In the title complex, [Cu(C(9)H(6)N(3)O(3)S)(2)(H(2)O)(4)]·2H(2)O, the Cu(II) atom lies on an inversion centre and is coordinated by four water mol­ecules in equatorial positions and two N atoms from two 4-(4-pyrid­yl)pyrimidine-2-sulfonate ligands in apical positions. The asymmetric unit contains h...

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Detalles Bibliográficos
Autores principales: Li, Lei, Xu, Gang, Zhu, Hai-Bin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977545/
https://www.ncbi.nlm.nih.gov/pubmed/21583731
http://dx.doi.org/10.1107/S1600536809011738
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author Li, Lei
Xu, Gang
Zhu, Hai-Bin
author_facet Li, Lei
Xu, Gang
Zhu, Hai-Bin
author_sort Li, Lei
collection PubMed
description In the title complex, [Cu(C(9)H(6)N(3)O(3)S)(2)(H(2)O)(4)]·2H(2)O, the Cu(II) atom lies on an inversion centre and is coordinated by four water mol­ecules in equatorial positions and two N atoms from two 4-(4-pyrid­yl)pyrimidine-2-sulfonate ligands in apical positions. The asymmetric unit contains half of the complex and one free water mol­ecule. The water mol­ecules, including the uncoordinated water mol­ecules, and sulfonate O atoms are involved in O—H⋯O and O—H⋯N hydrogen-bonding inter­actions.
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spelling pubmed-29775452010-12-30 Tetra­aqua­bis[4-(4-pyrid­yl)pyrimidine-2-sulfonato]copper(II) dihydrate Li, Lei Xu, Gang Zhu, Hai-Bin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cu(C(9)H(6)N(3)O(3)S)(2)(H(2)O)(4)]·2H(2)O, the Cu(II) atom lies on an inversion centre and is coordinated by four water mol­ecules in equatorial positions and two N atoms from two 4-(4-pyrid­yl)pyrimidine-2-sulfonate ligands in apical positions. The asymmetric unit contains half of the complex and one free water mol­ecule. The water mol­ecules, including the uncoordinated water mol­ecules, and sulfonate O atoms are involved in O—H⋯O and O—H⋯N hydrogen-bonding inter­actions. International Union of Crystallography 2009-04-02 /pmc/articles/PMC2977545/ /pubmed/21583731 http://dx.doi.org/10.1107/S1600536809011738 Text en © Li et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Lei
Xu, Gang
Zhu, Hai-Bin
Tetra­aqua­bis[4-(4-pyrid­yl)pyrimidine-2-sulfonato]copper(II) dihydrate
title Tetra­aqua­bis[4-(4-pyrid­yl)pyrimidine-2-sulfonato]copper(II) dihydrate
title_full Tetra­aqua­bis[4-(4-pyrid­yl)pyrimidine-2-sulfonato]copper(II) dihydrate
title_fullStr Tetra­aqua­bis[4-(4-pyrid­yl)pyrimidine-2-sulfonato]copper(II) dihydrate
title_full_unstemmed Tetra­aqua­bis[4-(4-pyrid­yl)pyrimidine-2-sulfonato]copper(II) dihydrate
title_short Tetra­aqua­bis[4-(4-pyrid­yl)pyrimidine-2-sulfonato]copper(II) dihydrate
title_sort tetra­aqua­bis[4-(4-pyrid­yl)pyrimidine-2-sulfonato]copper(ii) dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977545/
https://www.ncbi.nlm.nih.gov/pubmed/21583731
http://dx.doi.org/10.1107/S1600536809011738
work_keys_str_mv AT lilei tetraaquabis44pyridylpyrimidine2sulfonatocopperiidihydrate
AT xugang tetraaquabis44pyridylpyrimidine2sulfonatocopperiidihydrate
AT zhuhaibin tetraaquabis44pyridylpyrimidine2sulfonatocopperiidihydrate

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