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Bis(2,3-dimethyl­butane-2,3-diamine)nickel(II) dinitrate monohydrate

In the title compound, [Ni(C(6)H(16)N(2))(2)](NO(3))(2)·H(2)O, the bis­(2,3-dimethyl­butane-2,3-diamine)nickel(II) complex cation possesses a relatively undistorted square-planar geometry about the Ni atom, which lies on an inversion centre and is coordinated by four N atoms from two symmetry-relate...

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Detalles Bibliográficos
Autores principales: Li, Shen-Xin, Zou, Li-Ke, Xie, Bin, Wang, Jun, Li, Jian-Zhang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977546/
https://www.ncbi.nlm.nih.gov/pubmed/21583732
http://dx.doi.org/10.1107/S1600536809011702
Descripción
Sumario:In the title compound, [Ni(C(6)H(16)N(2))(2)](NO(3))(2)·H(2)O, the bis­(2,3-dimethyl­butane-2,3-diamine)nickel(II) complex cation possesses a relatively undistorted square-planar geometry about the Ni atom, which lies on an inversion centre and is coordinated by four N atoms from two symmetry-related 2,3-diamino-2,3-dimethyl­butane (tmen) ligands. The amine groups are N—H⋯O hydrogen bonded to the nitrate anions, which are, in turn, linked by inter­stitial water mol­ecules lying on a twofold axis. The infinite zigzag chains thus formed along [001] are further connected to each other by N—H⋯O hydrogen bonds towards the water mol­ecules, forming layers of two-dimensional hydrogen-bonded arrays.