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Bis(2,3-dimethylbutane-2,3-diamine)nickel(II) dinitrate monohydrate
In the title compound, [Ni(C(6)H(16)N(2))(2)](NO(3))(2)·H(2)O, the bis(2,3-dimethylbutane-2,3-diamine)nickel(II) complex cation possesses a relatively undistorted square-planar geometry about the Ni atom, which lies on an inversion centre and is coordinated by four N atoms from two symmetry-relate...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977546/ https://www.ncbi.nlm.nih.gov/pubmed/21583732 http://dx.doi.org/10.1107/S1600536809011702 |
Sumario: | In the title compound, [Ni(C(6)H(16)N(2))(2)](NO(3))(2)·H(2)O, the bis(2,3-dimethylbutane-2,3-diamine)nickel(II) complex cation possesses a relatively undistorted square-planar geometry about the Ni atom, which lies on an inversion centre and is coordinated by four N atoms from two symmetry-related 2,3-diamino-2,3-dimethylbutane (tmen) ligands. The amine groups are N—H⋯O hydrogen bonded to the nitrate anions, which are, in turn, linked by interstitial water molecules lying on a twofold axis. The infinite zigzag chains thus formed along [001] are further connected to each other by N—H⋯O hydrogen bonds towards the water molecules, forming layers of two-dimensional hydrogen-bonded arrays. |
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