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Bis(2,3-dimethyl­butane-2,3-diamine)nickel(II) dinitrate monohydrate

In the title compound, [Ni(C(6)H(16)N(2))(2)](NO(3))(2)·H(2)O, the bis­(2,3-dimethyl­butane-2,3-diamine)nickel(II) complex cation possesses a relatively undistorted square-planar geometry about the Ni atom, which lies on an inversion centre and is coordinated by four N atoms from two symmetry-relate...

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Detalles Bibliográficos
Autores principales: Li, Shen-Xin, Zou, Li-Ke, Xie, Bin, Wang, Jun, Li, Jian-Zhang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977546/
https://www.ncbi.nlm.nih.gov/pubmed/21583732
http://dx.doi.org/10.1107/S1600536809011702
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author Li, Shen-Xin
Zou, Li-Ke
Xie, Bin
Wang, Jun
Li, Jian-Zhang
author_facet Li, Shen-Xin
Zou, Li-Ke
Xie, Bin
Wang, Jun
Li, Jian-Zhang
author_sort Li, Shen-Xin
collection PubMed
description In the title compound, [Ni(C(6)H(16)N(2))(2)](NO(3))(2)·H(2)O, the bis­(2,3-dimethyl­butane-2,3-diamine)nickel(II) complex cation possesses a relatively undistorted square-planar geometry about the Ni atom, which lies on an inversion centre and is coordinated by four N atoms from two symmetry-related 2,3-diamino-2,3-dimethyl­butane (tmen) ligands. The amine groups are N—H⋯O hydrogen bonded to the nitrate anions, which are, in turn, linked by inter­stitial water mol­ecules lying on a twofold axis. The infinite zigzag chains thus formed along [001] are further connected to each other by N—H⋯O hydrogen bonds towards the water mol­ecules, forming layers of two-dimensional hydrogen-bonded arrays.
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spelling pubmed-29775462010-12-30 Bis(2,3-dimethyl­butane-2,3-diamine)nickel(II) dinitrate monohydrate Li, Shen-Xin Zou, Li-Ke Xie, Bin Wang, Jun Li, Jian-Zhang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(C(6)H(16)N(2))(2)](NO(3))(2)·H(2)O, the bis­(2,3-dimethyl­butane-2,3-diamine)nickel(II) complex cation possesses a relatively undistorted square-planar geometry about the Ni atom, which lies on an inversion centre and is coordinated by four N atoms from two symmetry-related 2,3-diamino-2,3-dimethyl­butane (tmen) ligands. The amine groups are N—H⋯O hydrogen bonded to the nitrate anions, which are, in turn, linked by inter­stitial water mol­ecules lying on a twofold axis. The infinite zigzag chains thus formed along [001] are further connected to each other by N—H⋯O hydrogen bonds towards the water mol­ecules, forming layers of two-dimensional hydrogen-bonded arrays. International Union of Crystallography 2009-04-02 /pmc/articles/PMC2977546/ /pubmed/21583732 http://dx.doi.org/10.1107/S1600536809011702 Text en © Li et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Shen-Xin
Zou, Li-Ke
Xie, Bin
Wang, Jun
Li, Jian-Zhang
Bis(2,3-dimethyl­butane-2,3-diamine)nickel(II) dinitrate monohydrate
title Bis(2,3-dimethyl­butane-2,3-diamine)nickel(II) dinitrate monohydrate
title_full Bis(2,3-dimethyl­butane-2,3-diamine)nickel(II) dinitrate monohydrate
title_fullStr Bis(2,3-dimethyl­butane-2,3-diamine)nickel(II) dinitrate monohydrate
title_full_unstemmed Bis(2,3-dimethyl­butane-2,3-diamine)nickel(II) dinitrate monohydrate
title_short Bis(2,3-dimethyl­butane-2,3-diamine)nickel(II) dinitrate monohydrate
title_sort bis(2,3-dimethyl­butane-2,3-diamine)nickel(ii) dinitrate monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977546/
https://www.ncbi.nlm.nih.gov/pubmed/21583732
http://dx.doi.org/10.1107/S1600536809011702
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