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Bis(2,3-dimethylbutane-2,3-diamine)nickel(II) dinitrate monohydrate
In the title compound, [Ni(C(6)H(16)N(2))(2)](NO(3))(2)·H(2)O, the bis(2,3-dimethylbutane-2,3-diamine)nickel(II) complex cation possesses a relatively undistorted square-planar geometry about the Ni atom, which lies on an inversion centre and is coordinated by four N atoms from two symmetry-relate...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977546/ https://www.ncbi.nlm.nih.gov/pubmed/21583732 http://dx.doi.org/10.1107/S1600536809011702 |
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author | Li, Shen-Xin Zou, Li-Ke Xie, Bin Wang, Jun Li, Jian-Zhang |
author_facet | Li, Shen-Xin Zou, Li-Ke Xie, Bin Wang, Jun Li, Jian-Zhang |
author_sort | Li, Shen-Xin |
collection | PubMed |
description | In the title compound, [Ni(C(6)H(16)N(2))(2)](NO(3))(2)·H(2)O, the bis(2,3-dimethylbutane-2,3-diamine)nickel(II) complex cation possesses a relatively undistorted square-planar geometry about the Ni atom, which lies on an inversion centre and is coordinated by four N atoms from two symmetry-related 2,3-diamino-2,3-dimethylbutane (tmen) ligands. The amine groups are N—H⋯O hydrogen bonded to the nitrate anions, which are, in turn, linked by interstitial water molecules lying on a twofold axis. The infinite zigzag chains thus formed along [001] are further connected to each other by N—H⋯O hydrogen bonds towards the water molecules, forming layers of two-dimensional hydrogen-bonded arrays. |
format | Text |
id | pubmed-2977546 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29775462010-12-30 Bis(2,3-dimethylbutane-2,3-diamine)nickel(II) dinitrate monohydrate Li, Shen-Xin Zou, Li-Ke Xie, Bin Wang, Jun Li, Jian-Zhang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(C(6)H(16)N(2))(2)](NO(3))(2)·H(2)O, the bis(2,3-dimethylbutane-2,3-diamine)nickel(II) complex cation possesses a relatively undistorted square-planar geometry about the Ni atom, which lies on an inversion centre and is coordinated by four N atoms from two symmetry-related 2,3-diamino-2,3-dimethylbutane (tmen) ligands. The amine groups are N—H⋯O hydrogen bonded to the nitrate anions, which are, in turn, linked by interstitial water molecules lying on a twofold axis. The infinite zigzag chains thus formed along [001] are further connected to each other by N—H⋯O hydrogen bonds towards the water molecules, forming layers of two-dimensional hydrogen-bonded arrays. International Union of Crystallography 2009-04-02 /pmc/articles/PMC2977546/ /pubmed/21583732 http://dx.doi.org/10.1107/S1600536809011702 Text en © Li et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Li, Shen-Xin Zou, Li-Ke Xie, Bin Wang, Jun Li, Jian-Zhang Bis(2,3-dimethylbutane-2,3-diamine)nickel(II) dinitrate monohydrate |
title | Bis(2,3-dimethylbutane-2,3-diamine)nickel(II) dinitrate monohydrate |
title_full | Bis(2,3-dimethylbutane-2,3-diamine)nickel(II) dinitrate monohydrate |
title_fullStr | Bis(2,3-dimethylbutane-2,3-diamine)nickel(II) dinitrate monohydrate |
title_full_unstemmed | Bis(2,3-dimethylbutane-2,3-diamine)nickel(II) dinitrate monohydrate |
title_short | Bis(2,3-dimethylbutane-2,3-diamine)nickel(II) dinitrate monohydrate |
title_sort | bis(2,3-dimethylbutane-2,3-diamine)nickel(ii) dinitrate monohydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977546/ https://www.ncbi.nlm.nih.gov/pubmed/21583732 http://dx.doi.org/10.1107/S1600536809011702 |
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