(Diethyl ether){1-[2-(1-methyl-1H-imidazol-2-yl-κN (3))-1,1-diphenyl­ethyl]-(1,2,3,3a,7a-η)-inden­yl}lithium(I)

In the title compound, [Li(C(27)H(23)N(2))(C(4)H(10)O)], the Li atom possesses a nearly planar trigonal coordination environment (assuming the cyclo­penta­dienyl ring of the indenyl group occupies one coordination place). The diethyl ether ligand adopts a nearly planar W-type conformation.

Detalles Bibliográficos
Autores principales: Sun, Guofeng, Tian, Chong, Nie, Wanli, Borzov, Maxim V.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977547/
https://www.ncbi.nlm.nih.gov/pubmed/21583733
http://dx.doi.org/10.1107/S1600536809011556
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author Sun, Guofeng
Tian, Chong
Nie, Wanli
Borzov, Maxim V.
author_facet Sun, Guofeng
Tian, Chong
Nie, Wanli
Borzov, Maxim V.
author_sort Sun, Guofeng
collection PubMed
description In the title compound, [Li(C(27)H(23)N(2))(C(4)H(10)O)], the Li atom possesses a nearly planar trigonal coordination environment (assuming the cyclo­penta­dienyl ring of the indenyl group occupies one coordination place). The diethyl ether ligand adopts a nearly planar W-type conformation.
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spelling pubmed-29775472010-12-30 (Diethyl ether){1-[2-(1-methyl-1H-imidazol-2-yl-κN (3))-1,1-diphenyl­ethyl]-(1,2,3,3a,7a-η)-inden­yl}lithium(I) Sun, Guofeng Tian, Chong Nie, Wanli Borzov, Maxim V. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Li(C(27)H(23)N(2))(C(4)H(10)O)], the Li atom possesses a nearly planar trigonal coordination environment (assuming the cyclo­penta­dienyl ring of the indenyl group occupies one coordination place). The diethyl ether ligand adopts a nearly planar W-type conformation. International Union of Crystallography 2009-04-02 /pmc/articles/PMC2977547/ /pubmed/21583733 http://dx.doi.org/10.1107/S1600536809011556 Text en © Sun et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Sun, Guofeng
Tian, Chong
Nie, Wanli
Borzov, Maxim V.
(Diethyl ether){1-[2-(1-methyl-1H-imidazol-2-yl-κN (3))-1,1-diphenyl­ethyl]-(1,2,3,3a,7a-η)-inden­yl}lithium(I)
title (Diethyl ether){1-[2-(1-methyl-1H-imidazol-2-yl-κN (3))-1,1-diphenyl­ethyl]-(1,2,3,3a,7a-η)-inden­yl}lithium(I)
title_full (Diethyl ether){1-[2-(1-methyl-1H-imidazol-2-yl-κN (3))-1,1-diphenyl­ethyl]-(1,2,3,3a,7a-η)-inden­yl}lithium(I)
title_fullStr (Diethyl ether){1-[2-(1-methyl-1H-imidazol-2-yl-κN (3))-1,1-diphenyl­ethyl]-(1,2,3,3a,7a-η)-inden­yl}lithium(I)
title_full_unstemmed (Diethyl ether){1-[2-(1-methyl-1H-imidazol-2-yl-κN (3))-1,1-diphenyl­ethyl]-(1,2,3,3a,7a-η)-inden­yl}lithium(I)
title_short (Diethyl ether){1-[2-(1-methyl-1H-imidazol-2-yl-κN (3))-1,1-diphenyl­ethyl]-(1,2,3,3a,7a-η)-inden­yl}lithium(I)
title_sort (diethyl ether){1-[2-(1-methyl-1h-imidazol-2-yl-κn (3))-1,1-diphenyl­ethyl]-(1,2,3,3a,7a-η)-inden­yl}lithium(i)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977547/
https://www.ncbi.nlm.nih.gov/pubmed/21583733
http://dx.doi.org/10.1107/S1600536809011556
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AT niewanli diethylether121methyl1himidazol2ylkn311diphenylethyl1233a7aēindenyllithiumi
AT borzovmaximv diethylether121methyl1himidazol2ylkn311diphenylethyl1233a7aēindenyllithiumi

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