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Diaqua­bis(2-bromo­benzoato-κO)bis­(N,N-diethyl­nicotinamide-κN (1))zinc(II)

In the centrosymmetric title complex, [Zn(C(7)H(4)BrO(2))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], the Zn(II) atom is located on an inversion center. The asymmetric unit contains one 2-bromo­benzoate (BB), one diethyl­nicotinamide (DENA) ligand and one coordinating water molecule. The four O atoms in the...

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Detalles Bibliográficos
Autores principales: Hökelek, Tuncer, Dal, Hakan, Tercan, Barış, Özbek, F. Elif, Necefoğlu, Hacali
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977549/
https://www.ncbi.nlm.nih.gov/pubmed/21583735
http://dx.doi.org/10.1107/S160053680901191X
Descripción
Sumario:In the centrosymmetric title complex, [Zn(C(7)H(4)BrO(2))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], the Zn(II) atom is located on an inversion center. The asymmetric unit contains one 2-bromo­benzoate (BB), one diethyl­nicotinamide (DENA) ligand and one coordinating water molecule. The four O atoms in the equatorial plane around the Zn atom form a slightly distorted square-planar arrangement, while the slightly distorted octa­hedral coordination is completed by the two N atoms of the DENA ligands in the axial positions. The dihedral angle between the carboxyl group and the adjacent benzene ring is 85.51 (12)°, while the pyridine and benzene rings are oriented at a dihedral angle of 44.07 (6)°. In the crystal structure, O—H⋯O hydrogen bonds link the mol­ecules into infinite chains.