Dibromido(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)mercury(II)

In the mol­ecule of the title compound, [HgBr(2)(C(14)H(12)N(2))], the Hg(II) atom is four-coordinated in a distorted tetra­hedral configuration by two N atoms from a 2,9-dimethyl-1,10-phenanthroline ligand and by two Br atoms. In the crystal structure, weak inter­molecular C—H⋯Br hydrogen bonds lin...

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Detalles Bibliográficos
Autores principales: Alizadeh, Robabeh, Heidari, Amene, Ahmadi, Roya, Amani, Vahid
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977550/
https://www.ncbi.nlm.nih.gov/pubmed/21583736
http://dx.doi.org/10.1107/S1600536809009994
Descripción
Sumario:In the mol­ecule of the title compound, [HgBr(2)(C(14)H(12)N(2))], the Hg(II) atom is four-coordinated in a distorted tetra­hedral configuration by two N atoms from a 2,9-dimethyl-1,10-phenanthroline ligand and by two Br atoms. In the crystal structure, weak inter­molecular C—H⋯Br hydrogen bonds link the mol­ecules into chains along the b axis. There are π–π contacts between the phenanthroline rings [centroid–centroid distances = 3.806 (4), 3.819 (4), 3.739 (3), 3.690 (3), 3.619 (4) and 3.674 (3) Å].

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