Dibromido(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)mercury(II)

In the mol­ecule of the title compound, [HgBr(2)(C(14)H(12)N(2))], the Hg(II) atom is four-coordinated in a distorted tetra­hedral configuration by two N atoms from a 2,9-dimethyl-1,10-phenanthroline ligand and by two Br atoms. In the crystal structure, weak inter­molecular C—H⋯Br hydrogen bonds lin...

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Detalles Bibliográficos
Autores principales: Alizadeh, Robabeh, Heidari, Amene, Ahmadi, Roya, Amani, Vahid
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977550/
https://www.ncbi.nlm.nih.gov/pubmed/21583736
http://dx.doi.org/10.1107/S1600536809009994
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author Alizadeh, Robabeh
Heidari, Amene
Ahmadi, Roya
Amani, Vahid
author_facet Alizadeh, Robabeh
Heidari, Amene
Ahmadi, Roya
Amani, Vahid
author_sort Alizadeh, Robabeh
collection PubMed
description In the mol­ecule of the title compound, [HgBr(2)(C(14)H(12)N(2))], the Hg(II) atom is four-coordinated in a distorted tetra­hedral configuration by two N atoms from a 2,9-dimethyl-1,10-phenanthroline ligand and by two Br atoms. In the crystal structure, weak inter­molecular C—H⋯Br hydrogen bonds link the mol­ecules into chains along the b axis. There are π–π contacts between the phenanthroline rings [centroid–centroid distances = 3.806 (4), 3.819 (4), 3.739 (3), 3.690 (3), 3.619 (4) and 3.674 (3) Å].
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spelling pubmed-29775502010-12-30 Dibromido(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)mercury(II) Alizadeh, Robabeh Heidari, Amene Ahmadi, Roya Amani, Vahid Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the mol­ecule of the title compound, [HgBr(2)(C(14)H(12)N(2))], the Hg(II) atom is four-coordinated in a distorted tetra­hedral configuration by two N atoms from a 2,9-dimethyl-1,10-phenanthroline ligand and by two Br atoms. In the crystal structure, weak inter­molecular C—H⋯Br hydrogen bonds link the mol­ecules into chains along the b axis. There are π–π contacts between the phenanthroline rings [centroid–centroid distances = 3.806 (4), 3.819 (4), 3.739 (3), 3.690 (3), 3.619 (4) and 3.674 (3) Å]. International Union of Crystallography 2009-04-02 /pmc/articles/PMC2977550/ /pubmed/21583736 http://dx.doi.org/10.1107/S1600536809009994 Text en © Alizadeh et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Alizadeh, Robabeh
Heidari, Amene
Ahmadi, Roya
Amani, Vahid
Dibromido(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)mercury(II)
title Dibromido(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)mercury(II)
title_full Dibromido(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)mercury(II)
title_fullStr Dibromido(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)mercury(II)
title_full_unstemmed Dibromido(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)mercury(II)
title_short Dibromido(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)mercury(II)
title_sort dibromido(2,9-dimethyl-1,10-phenanthroline-κ(2) n,n′)mercury(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977550/
https://www.ncbi.nlm.nih.gov/pubmed/21583736
http://dx.doi.org/10.1107/S1600536809009994
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AT heidariamene dibromido29dimethyl110phenanthrolinek2nnmercuryii
AT ahmadiroya dibromido29dimethyl110phenanthrolinek2nnmercuryii
AT amanivahid dibromido29dimethyl110phenanthrolinek2nnmercuryii

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