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Aqua(3-formyl-2-oxidobenzoato-κ(2) O (1),O (2))(1,10-phenanthroline-κ(2) N,N′)copper(II) dimethylformamide solvate
In the structure of the title complex, [Cu(C(8)H(4)O(4))(C(12)H(8)N(2))(H(2)O)]·C(3)H(7)NO, the Cu(II) ion is pentacoordinated in a distorted square-pyramidal geometry by two O atoms of a 3-formyl-2-oxidobenzoate dianion and two N atoms of a 1,10-phenanthroline ligand occupying the basal plane and...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977551/ https://www.ncbi.nlm.nih.gov/pubmed/21583737 http://dx.doi.org/10.1107/S1600536809011659 |
| _version_ | 1782191131170177024 |
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| author | Yu, Zhao-Wen Chang, Ling Song, Peng He, Min-Hui |
| author_facet | Yu, Zhao-Wen Chang, Ling Song, Peng He, Min-Hui |
| author_sort | Yu, Zhao-Wen |
| collection | PubMed |
| description | In the structure of the title complex, [Cu(C(8)H(4)O(4))(C(12)H(8)N(2))(H(2)O)]·C(3)H(7)NO, the Cu(II) ion is pentacoordinated in a distorted square-pyramidal geometry by two O atoms of a 3-formyl-2-oxidobenzoate dianion and two N atoms of a 1,10-phenanthroline ligand occupying the basal plane and a water O atom located at the apical site. The structure displays O—H⋯O hydrogen bonding and intermolecular π–π stacking interactions between 1,10-phenantroline ligands [interplanar distance of 3.448 (5) Å]. |
| format | Text |
| id | pubmed-2977551 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29775512010-12-30 Aqua(3-formyl-2-oxidobenzoato-κ(2) O (1),O (2))(1,10-phenanthroline-κ(2) N,N′)copper(II) dimethylformamide solvate Yu, Zhao-Wen Chang, Ling Song, Peng He, Min-Hui Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the structure of the title complex, [Cu(C(8)H(4)O(4))(C(12)H(8)N(2))(H(2)O)]·C(3)H(7)NO, the Cu(II) ion is pentacoordinated in a distorted square-pyramidal geometry by two O atoms of a 3-formyl-2-oxidobenzoate dianion and two N atoms of a 1,10-phenanthroline ligand occupying the basal plane and a water O atom located at the apical site. The structure displays O—H⋯O hydrogen bonding and intermolecular π–π stacking interactions between 1,10-phenantroline ligands [interplanar distance of 3.448 (5) Å]. International Union of Crystallography 2009-04-08 /pmc/articles/PMC2977551/ /pubmed/21583737 http://dx.doi.org/10.1107/S1600536809011659 Text en © Yu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Yu, Zhao-Wen Chang, Ling Song, Peng He, Min-Hui Aqua(3-formyl-2-oxidobenzoato-κ(2) O (1),O (2))(1,10-phenanthroline-κ(2) N,N′)copper(II) dimethylformamide solvate |
| title | Aqua(3-formyl-2-oxidobenzoato-κ(2)
O
(1),O
(2))(1,10-phenanthroline-κ(2)
N,N′)copper(II) dimethylformamide solvate |
| title_full | Aqua(3-formyl-2-oxidobenzoato-κ(2)
O
(1),O
(2))(1,10-phenanthroline-κ(2)
N,N′)copper(II) dimethylformamide solvate |
| title_fullStr | Aqua(3-formyl-2-oxidobenzoato-κ(2)
O
(1),O
(2))(1,10-phenanthroline-κ(2)
N,N′)copper(II) dimethylformamide solvate |
| title_full_unstemmed | Aqua(3-formyl-2-oxidobenzoato-κ(2)
O
(1),O
(2))(1,10-phenanthroline-κ(2)
N,N′)copper(II) dimethylformamide solvate |
| title_short | Aqua(3-formyl-2-oxidobenzoato-κ(2)
O
(1),O
(2))(1,10-phenanthroline-κ(2)
N,N′)copper(II) dimethylformamide solvate |
| title_sort | aqua(3-formyl-2-oxidobenzoato-κ(2)
o
(1),o
(2))(1,10-phenanthroline-κ(2)
n,n′)copper(ii) dimethylformamide solvate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977551/ https://www.ncbi.nlm.nih.gov/pubmed/21583737 http://dx.doi.org/10.1107/S1600536809011659 |
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