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Bis(μ-dithieno[3,2-b:2′,3′-d]thiophene-2,6-dicarboxylato-κ(2) O (2):O (6))bis[bis(1,10-phenanthroline-κ(2) N,N′)cobalt(II)] dimethylformamide disolvate
The asymmetric unit of the title compound, [Co(2)(C(10)H(2)O(4)S(3))(2)(C(12)H(8)N(2))(4)]·2C(3)H(7)NO, contains one half of the formula unit, with the rest generated by inversion. The cobalt ion sits in a slightly distorted octahedral environment and is ligated to four N atoms of two 1,10-phenanth...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977552/ https://www.ncbi.nlm.nih.gov/pubmed/21583738 http://dx.doi.org/10.1107/S1600536809011337 |
| _version_ | 1782191131401912320 |
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| author | MacNeill, Christopher M. Day, Cynthia S. Noftle, Ronald E. |
| author_facet | MacNeill, Christopher M. Day, Cynthia S. Noftle, Ronald E. |
| author_sort | MacNeill, Christopher M. |
| collection | PubMed |
| description | The asymmetric unit of the title compound, [Co(2)(C(10)H(2)O(4)S(3))(2)(C(12)H(8)N(2))(4)]·2C(3)H(7)NO, contains one half of the formula unit, with the rest generated by inversion. The cobalt ion sits in a slightly distorted octahedral environment and is ligated to four N atoms of two 1,10-phenanthroline molecules and to two O atoms of two dithieno[3,2-b:2′,3′-d]thiophene-2,6-dicarboxylate anions. The anions act as bridges between the Co(II) centers. |
| format | Text |
| id | pubmed-2977552 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29775522010-12-30 Bis(μ-dithieno[3,2-b:2′,3′-d]thiophene-2,6-dicarboxylato-κ(2) O (2):O (6))bis[bis(1,10-phenanthroline-κ(2) N,N′)cobalt(II)] dimethylformamide disolvate MacNeill, Christopher M. Day, Cynthia S. Noftle, Ronald E. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Co(2)(C(10)H(2)O(4)S(3))(2)(C(12)H(8)N(2))(4)]·2C(3)H(7)NO, contains one half of the formula unit, with the rest generated by inversion. The cobalt ion sits in a slightly distorted octahedral environment and is ligated to four N atoms of two 1,10-phenanthroline molecules and to two O atoms of two dithieno[3,2-b:2′,3′-d]thiophene-2,6-dicarboxylate anions. The anions act as bridges between the Co(II) centers. International Union of Crystallography 2009-04-08 /pmc/articles/PMC2977552/ /pubmed/21583738 http://dx.doi.org/10.1107/S1600536809011337 Text en © MacNeill et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers MacNeill, Christopher M. Day, Cynthia S. Noftle, Ronald E. Bis(μ-dithieno[3,2-b:2′,3′-d]thiophene-2,6-dicarboxylato-κ(2) O (2):O (6))bis[bis(1,10-phenanthroline-κ(2) N,N′)cobalt(II)] dimethylformamide disolvate |
| title | Bis(μ-dithieno[3,2-b:2′,3′-d]thiophene-2,6-dicarboxylato-κ(2)
O
(2):O
(6))bis[bis(1,10-phenanthroline-κ(2)
N,N′)cobalt(II)] dimethylformamide disolvate |
| title_full | Bis(μ-dithieno[3,2-b:2′,3′-d]thiophene-2,6-dicarboxylato-κ(2)
O
(2):O
(6))bis[bis(1,10-phenanthroline-κ(2)
N,N′)cobalt(II)] dimethylformamide disolvate |
| title_fullStr | Bis(μ-dithieno[3,2-b:2′,3′-d]thiophene-2,6-dicarboxylato-κ(2)
O
(2):O
(6))bis[bis(1,10-phenanthroline-κ(2)
N,N′)cobalt(II)] dimethylformamide disolvate |
| title_full_unstemmed | Bis(μ-dithieno[3,2-b:2′,3′-d]thiophene-2,6-dicarboxylato-κ(2)
O
(2):O
(6))bis[bis(1,10-phenanthroline-κ(2)
N,N′)cobalt(II)] dimethylformamide disolvate |
| title_short | Bis(μ-dithieno[3,2-b:2′,3′-d]thiophene-2,6-dicarboxylato-κ(2)
O
(2):O
(6))bis[bis(1,10-phenanthroline-κ(2)
N,N′)cobalt(II)] dimethylformamide disolvate |
| title_sort | bis(μ-dithieno[3,2-b:2′,3′-d]thiophene-2,6-dicarboxylato-κ(2)
o
(2):o
(6))bis[bis(1,10-phenanthroline-κ(2)
n,n′)cobalt(ii)] dimethylformamide disolvate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977552/ https://www.ncbi.nlm.nih.gov/pubmed/21583738 http://dx.doi.org/10.1107/S1600536809011337 |
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