2-[3-(2-Pyrid­yl)pyrazin-2-yl]pyridinium tetra­chloridoaurate(III)

In the anion of the title compound, (C(14)H(11)N(4))[AuCl(4)], the Au(III) atom has an almost perfect square-planar coordination. In the crystal structure, an intra­molecular N—H⋯N and intermolecular C—H⋯Cl hydrogen bonds are observed. In addition, there is also a ring–metal inter­action between the...

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Autores principales: Yıldırım, Sema Öztürk, Akkurt, Mehmet, Safari, Nasser, Amani, Vahid, McKee, Vickie
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977556/
https://www.ncbi.nlm.nih.gov/pubmed/21583742
http://dx.doi.org/10.1107/S1600536809012264
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author Yıldırım, Sema Öztürk
Akkurt, Mehmet
Safari, Nasser
Amani, Vahid
McKee, Vickie
author_facet Yıldırım, Sema Öztürk
Akkurt, Mehmet
Safari, Nasser
Amani, Vahid
McKee, Vickie
author_sort Yıldırım, Sema Öztürk
collection PubMed
description In the anion of the title compound, (C(14)H(11)N(4))[AuCl(4)], the Au(III) atom has an almost perfect square-planar coordination. In the crystal structure, an intra­molecular N—H⋯N and intermolecular C—H⋯Cl hydrogen bonds are observed. In addition, there is also a ring–metal inter­action between the pyrazine ring and the Au(III) atom; the distance between the centroid of the pyrazine ring and the Au(III) atom is 3.628 (2) Å.
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spelling pubmed-29775562010-12-30 2-[3-(2-Pyrid­yl)pyrazin-2-yl]pyridinium tetra­chloridoaurate(III) Yıldırım, Sema Öztürk Akkurt, Mehmet Safari, Nasser Amani, Vahid McKee, Vickie Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the anion of the title compound, (C(14)H(11)N(4))[AuCl(4)], the Au(III) atom has an almost perfect square-planar coordination. In the crystal structure, an intra­molecular N—H⋯N and intermolecular C—H⋯Cl hydrogen bonds are observed. In addition, there is also a ring–metal inter­action between the pyrazine ring and the Au(III) atom; the distance between the centroid of the pyrazine ring and the Au(III) atom is 3.628 (2) Å. International Union of Crystallography 2009-04-08 /pmc/articles/PMC2977556/ /pubmed/21583742 http://dx.doi.org/10.1107/S1600536809012264 Text en © Yıldırım et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yıldırım, Sema Öztürk
Akkurt, Mehmet
Safari, Nasser
Amani, Vahid
McKee, Vickie
2-[3-(2-Pyrid­yl)pyrazin-2-yl]pyridinium tetra­chloridoaurate(III)
title 2-[3-(2-Pyrid­yl)pyrazin-2-yl]pyridinium tetra­chloridoaurate(III)
title_full 2-[3-(2-Pyrid­yl)pyrazin-2-yl]pyridinium tetra­chloridoaurate(III)
title_fullStr 2-[3-(2-Pyrid­yl)pyrazin-2-yl]pyridinium tetra­chloridoaurate(III)
title_full_unstemmed 2-[3-(2-Pyrid­yl)pyrazin-2-yl]pyridinium tetra­chloridoaurate(III)
title_short 2-[3-(2-Pyrid­yl)pyrazin-2-yl]pyridinium tetra­chloridoaurate(III)
title_sort 2-[3-(2-pyrid­yl)pyrazin-2-yl]pyridinium tetra­chloridoaurate(iii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977556/
https://www.ncbi.nlm.nih.gov/pubmed/21583742
http://dx.doi.org/10.1107/S1600536809012264
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AT safarinasser 232pyridylpyrazin2ylpyridiniumtetrachloridoaurateiii
AT amanivahid 232pyridylpyrazin2ylpyridiniumtetrachloridoaurateiii
AT mckeevickie 232pyridylpyrazin2ylpyridiniumtetrachloridoaurateiii

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