(Biphenyl-2-yl)bromidobis(2-methyl­tetra­hydro­furan-κO)magnesium(II)

In the title Grignard reagent, [MgBr(C(12)H(9))(C(5)H(10)O)(2)], the Mg centre adopts a distorted tetra­hedral MgCO(2)Br arrangement. The dihedral angle between the two aromatic rings of the biphenyl residue is 44.00 (14)°. Each mol­ecule incorporates one R- and one S-configured 2-methyl­tetra­hydro...

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Detalles Bibliográficos
Autores principales: Nordschild, Simon, Wohlgemuth, D., Bolte, Michael
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977557/
https://www.ncbi.nlm.nih.gov/pubmed/21583743
http://dx.doi.org/10.1107/S1600536809012185
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author Nordschild, Simon
Wohlgemuth, D.
Bolte, Michael
author_facet Nordschild, Simon
Wohlgemuth, D.
Bolte, Michael
author_sort Nordschild, Simon
collection PubMed
description In the title Grignard reagent, [MgBr(C(12)H(9))(C(5)H(10)O)(2)], the Mg centre adopts a distorted tetra­hedral MgCO(2)Br arrangement. The dihedral angle between the two aromatic rings of the biphenyl residue is 44.00 (14)°. Each mol­ecule incorporates one R- and one S-configured 2-methyl­tetra­hydro­furan mol­ecule.
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spelling pubmed-29775572010-12-30 (Biphenyl-2-yl)bromidobis(2-methyl­tetra­hydro­furan-κO)magnesium(II) Nordschild, Simon Wohlgemuth, D. Bolte, Michael Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title Grignard reagent, [MgBr(C(12)H(9))(C(5)H(10)O)(2)], the Mg centre adopts a distorted tetra­hedral MgCO(2)Br arrangement. The dihedral angle between the two aromatic rings of the biphenyl residue is 44.00 (14)°. Each mol­ecule incorporates one R- and one S-configured 2-methyl­tetra­hydro­furan mol­ecule. International Union of Crystallography 2009-04-08 /pmc/articles/PMC2977557/ /pubmed/21583743 http://dx.doi.org/10.1107/S1600536809012185 Text en © Nordschild et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Nordschild, Simon
Wohlgemuth, D.
Bolte, Michael
(Biphenyl-2-yl)bromidobis(2-methyl­tetra­hydro­furan-κO)magnesium(II)
title (Biphenyl-2-yl)bromidobis(2-methyl­tetra­hydro­furan-κO)magnesium(II)
title_full (Biphenyl-2-yl)bromidobis(2-methyl­tetra­hydro­furan-κO)magnesium(II)
title_fullStr (Biphenyl-2-yl)bromidobis(2-methyl­tetra­hydro­furan-κO)magnesium(II)
title_full_unstemmed (Biphenyl-2-yl)bromidobis(2-methyl­tetra­hydro­furan-κO)magnesium(II)
title_short (Biphenyl-2-yl)bromidobis(2-methyl­tetra­hydro­furan-κO)magnesium(II)
title_sort (biphenyl-2-yl)bromidobis(2-methyl­tetra­hydro­furan-κo)magnesium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977557/
https://www.ncbi.nlm.nih.gov/pubmed/21583743
http://dx.doi.org/10.1107/S1600536809012185
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AT wohlgemuthd biphenyl2ylbromidobis2methyltetrahydrofurankomagnesiumii
AT boltemichael biphenyl2ylbromidobis2methyltetrahydrofurankomagnesiumii

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