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(2,6-Difluorobenzophenone)tris(trimethylphosphine)cobalt(0)
In the title compound, [Co(C(13)H(8)F(2)O)(C(3)H(9)P)(3)], the cobalt(0) atom is coordinated by three trimethylphosphine ligands and a π-coordinated carbonyl group of the 2,6-difluorobenzophenone ligand in a distorted tetrahedral geometry. The Co—O and Co—C distances are 1.896 (2) and 2.049 (4) ...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977559/ https://www.ncbi.nlm.nih.gov/pubmed/21583745 http://dx.doi.org/10.1107/S1600536809012367 |
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author | Ding, Jun Li, Xiao-Yan |
author_facet | Ding, Jun Li, Xiao-Yan |
author_sort | Ding, Jun |
collection | PubMed |
description | In the title compound, [Co(C(13)H(8)F(2)O)(C(3)H(9)P)(3)], the cobalt(0) atom is coordinated by three trimethylphosphine ligands and a π-coordinated carbonyl group of the 2,6-difluorobenzophenone ligand in a distorted tetrahedral geometry. The Co—O and Co—C distances are 1.896 (2) and 2.049 (4) Å, respectively. |
format | Text |
id | pubmed-2977559 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29775592010-12-30 (2,6-Difluorobenzophenone)tris(trimethylphosphine)cobalt(0) Ding, Jun Li, Xiao-Yan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(C(13)H(8)F(2)O)(C(3)H(9)P)(3)], the cobalt(0) atom is coordinated by three trimethylphosphine ligands and a π-coordinated carbonyl group of the 2,6-difluorobenzophenone ligand in a distorted tetrahedral geometry. The Co—O and Co—C distances are 1.896 (2) and 2.049 (4) Å, respectively. International Union of Crystallography 2009-04-08 /pmc/articles/PMC2977559/ /pubmed/21583745 http://dx.doi.org/10.1107/S1600536809012367 Text en © Ding and Li 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Ding, Jun Li, Xiao-Yan (2,6-Difluorobenzophenone)tris(trimethylphosphine)cobalt(0) |
title | (2,6-Difluorobenzophenone)tris(trimethylphosphine)cobalt(0) |
title_full | (2,6-Difluorobenzophenone)tris(trimethylphosphine)cobalt(0) |
title_fullStr | (2,6-Difluorobenzophenone)tris(trimethylphosphine)cobalt(0) |
title_full_unstemmed | (2,6-Difluorobenzophenone)tris(trimethylphosphine)cobalt(0) |
title_short | (2,6-Difluorobenzophenone)tris(trimethylphosphine)cobalt(0) |
title_sort | (2,6-difluorobenzophenone)tris(trimethylphosphine)cobalt(0) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977559/ https://www.ncbi.nlm.nih.gov/pubmed/21583745 http://dx.doi.org/10.1107/S1600536809012367 |
work_keys_str_mv | AT dingjun 26difluorobenzophenonetristrimethylphosphinecobalt0 AT lixiaoyan 26difluorobenzophenonetristrimethylphosphinecobalt0 |