catena-Poly[sodium(I)-μ-tetra­butoxy­borato]

The title compound, [Na(C(16)H(36)BO(4))](n), has a fourfold axis passing through the Na and B atoms which both are bound by four O atoms. The tetra­butoxy­borate anion provides the bridging to form one-dimensional polymers running along [001], just like those found for the tetra­ethoxy­borate struc...

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Detalles Bibliográficos
Autores principales: Gainsford, Graeme J., Kemmitt, Tim
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977560/
https://www.ncbi.nlm.nih.gov/pubmed/21583746
http://dx.doi.org/10.1107/S1600536809012100
Descripción
Sumario:The title compound, [Na(C(16)H(36)BO(4))](n), has a fourfold axis passing through the Na and B atoms which both are bound by four O atoms. The tetra­butoxy­borate anion provides the bridging to form one-dimensional polymers running along [001], just like those found for the tetra­ethoxy­borate structure. The two but­oxy ‘tail’ atoms are disordered over two conformations in a 0.887 (9):0.113 (9) ratio.

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