catena-Poly[sodium(I)-μ-tetra­butoxy­borato]

The title compound, [Na(C(16)H(36)BO(4))](n), has a fourfold axis passing through the Na and B atoms which both are bound by four O atoms. The tetra­butoxy­borate anion provides the bridging to form one-dimensional polymers running along [001], just like those found for the tetra­ethoxy­borate struc...

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Detalles Bibliográficos
Autores principales: Gainsford, Graeme J., Kemmitt, Tim
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977560/
https://www.ncbi.nlm.nih.gov/pubmed/21583746
http://dx.doi.org/10.1107/S1600536809012100
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author Gainsford, Graeme J.
Kemmitt, Tim
author_facet Gainsford, Graeme J.
Kemmitt, Tim
author_sort Gainsford, Graeme J.
collection PubMed
description The title compound, [Na(C(16)H(36)BO(4))](n), has a fourfold axis passing through the Na and B atoms which both are bound by four O atoms. The tetra­butoxy­borate anion provides the bridging to form one-dimensional polymers running along [001], just like those found for the tetra­ethoxy­borate structure. The two but­oxy ‘tail’ atoms are disordered over two conformations in a 0.887 (9):0.113 (9) ratio.
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spelling pubmed-29775602010-12-30 catena-Poly[sodium(I)-μ-tetra­butoxy­borato] Gainsford, Graeme J. Kemmitt, Tim Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Na(C(16)H(36)BO(4))](n), has a fourfold axis passing through the Na and B atoms which both are bound by four O atoms. The tetra­butoxy­borate anion provides the bridging to form one-dimensional polymers running along [001], just like those found for the tetra­ethoxy­borate structure. The two but­oxy ‘tail’ atoms are disordered over two conformations in a 0.887 (9):0.113 (9) ratio. International Union of Crystallography 2009-04-08 /pmc/articles/PMC2977560/ /pubmed/21583746 http://dx.doi.org/10.1107/S1600536809012100 Text en © Gainsford and Kemmitt 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Gainsford, Graeme J.
Kemmitt, Tim
catena-Poly[sodium(I)-μ-tetra­butoxy­borato]
title catena-Poly[sodium(I)-μ-tetra­butoxy­borato]
title_full catena-Poly[sodium(I)-μ-tetra­butoxy­borato]
title_fullStr catena-Poly[sodium(I)-μ-tetra­butoxy­borato]
title_full_unstemmed catena-Poly[sodium(I)-μ-tetra­butoxy­borato]
title_short catena-Poly[sodium(I)-μ-tetra­butoxy­borato]
title_sort catena-poly[sodium(i)-μ-tetra­butoxy­borato]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977560/
https://www.ncbi.nlm.nih.gov/pubmed/21583746
http://dx.doi.org/10.1107/S1600536809012100
work_keys_str_mv AT gainsfordgraemej catenapolysodiumimtetrabutoxyborato
AT kemmitttim catenapolysodiumimtetrabutoxyborato

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