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Bis[cis-bis(diphenylphosphino)ethene-κ (2) P,P′]copper(I) tetrafluoridoborate ethanol solvate
In the title compound [Cu(C(26)H(22)P(2))(2)]BF(4)·C(2)H(5)OH, a disordered ethanol solvate molecule and the anions are located in well defined channels along the c axis. The four-coordinate Cu(P—P)(2) core of the cation adopts approximately D (2) point group symmetry with the Cu—P bond lengths span...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977563/ https://www.ncbi.nlm.nih.gov/pubmed/21583749 http://dx.doi.org/10.1107/S1600536809012707 |
| _version_ | 1782191134251941888 |
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| author | Healy, Peter C. Loughrey, Bradley T. Williams, Michael L. |
| author_facet | Healy, Peter C. Loughrey, Bradley T. Williams, Michael L. |
| author_sort | Healy, Peter C. |
| collection | PubMed |
| description | In the title compound [Cu(C(26)H(22)P(2))(2)]BF(4)·C(2)H(5)OH, a disordered ethanol solvate molecule and the anions are located in well defined channels along the c axis. The four-coordinate Cu(P—P)(2) core of the cation adopts approximately D (2) point group symmetry with the Cu—P bond lengths spanning a narrow range from 2.272 (1) to 2.285 (1) Å. |
| format | Text |
| id | pubmed-2977563 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29775632010-12-30 Bis[cis-bis(diphenylphosphino)ethene-κ (2) P,P′]copper(I) tetrafluoridoborate ethanol solvate Healy, Peter C. Loughrey, Bradley T. Williams, Michael L. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound [Cu(C(26)H(22)P(2))(2)]BF(4)·C(2)H(5)OH, a disordered ethanol solvate molecule and the anions are located in well defined channels along the c axis. The four-coordinate Cu(P—P)(2) core of the cation adopts approximately D (2) point group symmetry with the Cu—P bond lengths spanning a narrow range from 2.272 (1) to 2.285 (1) Å. International Union of Crystallography 2009-04-08 /pmc/articles/PMC2977563/ /pubmed/21583749 http://dx.doi.org/10.1107/S1600536809012707 Text en © Healy et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Healy, Peter C. Loughrey, Bradley T. Williams, Michael L. Bis[cis-bis(diphenylphosphino)ethene-κ (2) P,P′]copper(I) tetrafluoridoborate ethanol solvate |
| title | Bis[cis-bis(diphenylphosphino)ethene-κ
(2)
P,P′]copper(I) tetrafluoridoborate ethanol solvate |
| title_full | Bis[cis-bis(diphenylphosphino)ethene-κ
(2)
P,P′]copper(I) tetrafluoridoborate ethanol solvate |
| title_fullStr | Bis[cis-bis(diphenylphosphino)ethene-κ
(2)
P,P′]copper(I) tetrafluoridoborate ethanol solvate |
| title_full_unstemmed | Bis[cis-bis(diphenylphosphino)ethene-κ
(2)
P,P′]copper(I) tetrafluoridoborate ethanol solvate |
| title_short | Bis[cis-bis(diphenylphosphino)ethene-κ
(2)
P,P′]copper(I) tetrafluoridoborate ethanol solvate |
| title_sort | bis[cis-bis(diphenylphosphino)ethene-κ
(2)
p,p′]copper(i) tetrafluoridoborate ethanol solvate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977563/ https://www.ncbi.nlm.nih.gov/pubmed/21583749 http://dx.doi.org/10.1107/S1600536809012707 |
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