Cargando…
Poly[di-μ(2)-azido-μ(3)-pyrazine-2-carboxylato-cadmium(II)]
The title compound, [Cd(C(5)H(3)N(2)O(2))(N(3))](n), has been prepared by the reaction of pyrazine-2-carboxylic acid, cadmium(II) nitrate and sodium azide. In the structure, the Cd(II) atom is six-coordinated by two azide anions and three pyrazine-2-carboxylate ligands. Each pyrazine-2-carboxylat...
| Autores principales: | , , |
|---|---|
| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977564/ https://www.ncbi.nlm.nih.gov/pubmed/21583750 http://dx.doi.org/10.1107/S1600536809012227 |
| _version_ | 1782191134487871488 |
|---|---|
| author | Li, Cai-Yun Li, Pei-Fan Jin, Hui-Min |
| author_facet | Li, Cai-Yun Li, Pei-Fan Jin, Hui-Min |
| author_sort | Li, Cai-Yun |
| collection | PubMed |
| description | The title compound, [Cd(C(5)H(3)N(2)O(2))(N(3))](n), has been prepared by the reaction of pyrazine-2-carboxylic acid, cadmium(II) nitrate and sodium azide. In the structure, the Cd(II) atom is six-coordinated by two azide anions and three pyrazine-2-carboxylate ligands. Each pyrazine-2-carboxylate ligand bridges three Cd(II) atoms, whereas the azide ligand bridges two Cd(II) atoms, resulting in the formation of a two-dimensional metal–organic polymer developing parallel to the (100) plane. |
| format | Text |
| id | pubmed-2977564 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29775642010-12-30 Poly[di-μ(2)-azido-μ(3)-pyrazine-2-carboxylato-cadmium(II)] Li, Cai-Yun Li, Pei-Fan Jin, Hui-Min Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cd(C(5)H(3)N(2)O(2))(N(3))](n), has been prepared by the reaction of pyrazine-2-carboxylic acid, cadmium(II) nitrate and sodium azide. In the structure, the Cd(II) atom is six-coordinated by two azide anions and three pyrazine-2-carboxylate ligands. Each pyrazine-2-carboxylate ligand bridges three Cd(II) atoms, whereas the azide ligand bridges two Cd(II) atoms, resulting in the formation of a two-dimensional metal–organic polymer developing parallel to the (100) plane. International Union of Crystallography 2009-04-10 /pmc/articles/PMC2977564/ /pubmed/21583750 http://dx.doi.org/10.1107/S1600536809012227 Text en © Li et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Li, Cai-Yun Li, Pei-Fan Jin, Hui-Min Poly[di-μ(2)-azido-μ(3)-pyrazine-2-carboxylato-cadmium(II)] |
| title | Poly[di-μ(2)-azido-μ(3)-pyrazine-2-carboxylato-cadmium(II)] |
| title_full | Poly[di-μ(2)-azido-μ(3)-pyrazine-2-carboxylato-cadmium(II)] |
| title_fullStr | Poly[di-μ(2)-azido-μ(3)-pyrazine-2-carboxylato-cadmium(II)] |
| title_full_unstemmed | Poly[di-μ(2)-azido-μ(3)-pyrazine-2-carboxylato-cadmium(II)] |
| title_short | Poly[di-μ(2)-azido-μ(3)-pyrazine-2-carboxylato-cadmium(II)] |
| title_sort | poly[di-μ(2)-azido-μ(3)-pyrazine-2-carboxylato-cadmium(ii)] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977564/ https://www.ncbi.nlm.nih.gov/pubmed/21583750 http://dx.doi.org/10.1107/S1600536809012227 |
| work_keys_str_mv | AT licaiyun polydim2azidom3pyrazine2carboxylatocadmiumii AT lipeifan polydim2azidom3pyrazine2carboxylatocadmiumii AT jinhuimin polydim2azidom3pyrazine2carboxylatocadmiumii |