Bis(guanidinium) tetra­iodidomercurate(II)

The Hg atom in the crystal structure of the title compound, (CH(6)N(3))(2)[HgI(4)], is tetra­hedrally coordinated by four I atoms. The [HgI(4)](2−) ions are inter­connected to the [C(NH(2))(3)](+) ions by N—H⋯I hydrogen bonds, forming a three-dimensional network. The four different observed Hg—I dis...

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Autores principales: Terao, Hiromitsu, Gesing, Thorsten M., Ishihara, Hideta, Furukawa, Yoshihiro, Gowda, B. Thimme
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977565/
https://www.ncbi.nlm.nih.gov/pubmed/21583751
http://dx.doi.org/10.1107/S160053680901280X
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author Terao, Hiromitsu
Gesing, Thorsten M.
Ishihara, Hideta
Furukawa, Yoshihiro
Gowda, B. Thimme
author_facet Terao, Hiromitsu
Gesing, Thorsten M.
Ishihara, Hideta
Furukawa, Yoshihiro
Gowda, B. Thimme
author_sort Terao, Hiromitsu
collection PubMed
description The Hg atom in the crystal structure of the title compound, (CH(6)N(3))(2)[HgI(4)], is tetra­hedrally coordinated by four I atoms. The [HgI(4)](2−) ions are inter­connected to the [C(NH(2))(3)](+) ions by N—H⋯I hydrogen bonds, forming a three-dimensional network. The four different observed Hg—I distances [2.760 (2), 2.7762 (15), 2.8098 (14) and 2.833 (2) Å] are consistent with four different (127)I NQR frequencies observed, showing the existence of four unique I atoms in the tetra­iodidomercurate unit.
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spelling pubmed-29775652010-12-30 Bis(guanidinium) tetra­iodidomercurate(II) Terao, Hiromitsu Gesing, Thorsten M. Ishihara, Hideta Furukawa, Yoshihiro Gowda, B. Thimme Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Hg atom in the crystal structure of the title compound, (CH(6)N(3))(2)[HgI(4)], is tetra­hedrally coordinated by four I atoms. The [HgI(4)](2−) ions are inter­connected to the [C(NH(2))(3)](+) ions by N—H⋯I hydrogen bonds, forming a three-dimensional network. The four different observed Hg—I distances [2.760 (2), 2.7762 (15), 2.8098 (14) and 2.833 (2) Å] are consistent with four different (127)I NQR frequencies observed, showing the existence of four unique I atoms in the tetra­iodidomercurate unit. International Union of Crystallography 2009-04-10 /pmc/articles/PMC2977565/ /pubmed/21583751 http://dx.doi.org/10.1107/S160053680901280X Text en © Terao et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Terao, Hiromitsu
Gesing, Thorsten M.
Ishihara, Hideta
Furukawa, Yoshihiro
Gowda, B. Thimme
Bis(guanidinium) tetra­iodidomercurate(II)
title Bis(guanidinium) tetra­iodidomercurate(II)
title_full Bis(guanidinium) tetra­iodidomercurate(II)
title_fullStr Bis(guanidinium) tetra­iodidomercurate(II)
title_full_unstemmed Bis(guanidinium) tetra­iodidomercurate(II)
title_short Bis(guanidinium) tetra­iodidomercurate(II)
title_sort bis(guanidinium) tetra­iodidomercurate(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977565/
https://www.ncbi.nlm.nih.gov/pubmed/21583751
http://dx.doi.org/10.1107/S160053680901280X
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AT gesingthorstenm bisguanidiniumtetraiodidomercurateii
AT ishiharahideta bisguanidiniumtetraiodidomercurateii
AT furukawayoshihiro bisguanidiniumtetraiodidomercurateii
AT gowdabthimme bisguanidiniumtetraiodidomercurateii

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