Diaqua­bis(5-carb­oxy-2-methyl-1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4))cobalt(II) dimethyl­formamide disolvate

In the title compound, [Co(C(6)H(5)N(2)O(4))(2)(H(2)O)(2)]·2C(3)H(7)NO, the Co(II) ion lies on an inversion center and adopts a slightly distorted CoN(2)O(4) octa­hedral geometry binding two bidentate chelating 5-carb­oxy-2-methyl-1H-imidazole-4-carboxyl­ate (H(2)MIDA(−)) monoanionic ligands and two...

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Detalles Bibliográficos
Autor principal: Tang, Si-Ping
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977566/
https://www.ncbi.nlm.nih.gov/pubmed/21583752
http://dx.doi.org/10.1107/S1600536809012902
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author Tang, Si-Ping
author_facet Tang, Si-Ping
author_sort Tang, Si-Ping
collection PubMed
description In the title compound, [Co(C(6)H(5)N(2)O(4))(2)(H(2)O)(2)]·2C(3)H(7)NO, the Co(II) ion lies on an inversion center and adopts a slightly distorted CoN(2)O(4) octa­hedral geometry binding two bidentate chelating 5-carb­oxy-2-methyl-1H-imidazole-4-carboxyl­ate (H(2)MIDA(−)) monoanionic ligands and two axial aqua ligands. In the crystal structure, inter­molecular O—H⋯O hydrogen bonds link neighboring mol­ecules, generating a two-dimensional framework containing eight-membered H(4)O(4) rings. In addition, the dimethyl­formamide solvent mol­ecules are hydrogen bonded to the two-dimensional framework via the NH groups of the H(2)MIDA(−) ligands.
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spelling pubmed-29775662010-12-30 Diaqua­bis(5-carb­oxy-2-methyl-1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4))cobalt(II) dimethyl­formamide disolvate Tang, Si-Ping Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(C(6)H(5)N(2)O(4))(2)(H(2)O)(2)]·2C(3)H(7)NO, the Co(II) ion lies on an inversion center and adopts a slightly distorted CoN(2)O(4) octa­hedral geometry binding two bidentate chelating 5-carb­oxy-2-methyl-1H-imidazole-4-carboxyl­ate (H(2)MIDA(−)) monoanionic ligands and two axial aqua ligands. In the crystal structure, inter­molecular O—H⋯O hydrogen bonds link neighboring mol­ecules, generating a two-dimensional framework containing eight-membered H(4)O(4) rings. In addition, the dimethyl­formamide solvent mol­ecules are hydrogen bonded to the two-dimensional framework via the NH groups of the H(2)MIDA(−) ligands. International Union of Crystallography 2009-04-10 /pmc/articles/PMC2977566/ /pubmed/21583752 http://dx.doi.org/10.1107/S1600536809012902 Text en © Si-Ping Tang 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Tang, Si-Ping
Diaqua­bis(5-carb­oxy-2-methyl-1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4))cobalt(II) dimethyl­formamide disolvate
title Diaqua­bis(5-carb­oxy-2-methyl-1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4))cobalt(II) dimethyl­formamide disolvate
title_full Diaqua­bis(5-carb­oxy-2-methyl-1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4))cobalt(II) dimethyl­formamide disolvate
title_fullStr Diaqua­bis(5-carb­oxy-2-methyl-1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4))cobalt(II) dimethyl­formamide disolvate
title_full_unstemmed Diaqua­bis(5-carb­oxy-2-methyl-1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4))cobalt(II) dimethyl­formamide disolvate
title_short Diaqua­bis(5-carb­oxy-2-methyl-1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4))cobalt(II) dimethyl­formamide disolvate
title_sort diaqua­bis(5-carb­oxy-2-methyl-1h-imidazole-4-carboxyl­ato-κ(2) n (3),o (4))cobalt(ii) dimethyl­formamide disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977566/
https://www.ncbi.nlm.nih.gov/pubmed/21583752
http://dx.doi.org/10.1107/S1600536809012902
work_keys_str_mv AT tangsiping diaquabis5carboxy2methyl1himidazole4carboxylatok2n3o4cobaltiidimethylformamidedisolvate

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