Poly[μ(2)-chlorido-(μ(2)-3H (+)-1,3,4-thia­diazo­lium-2-thiol­ato-κ(2) S:S)silver(I)]

In the title compound, [AgCl(C(2)H(2)N(2)S(2))](n), the Ag(I) ion has a distorted tetra­hedral geometry, defined by two S atoms of two symmetry-related 1,3,4-thia­diazo­lium-2-thiol­ate ligands and two chloride ions. The Ag(I) ions are bridged into a two-dimensional network parallel to the ab plane...

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Detalles Bibliográficos
Autores principales: Wang, Jian-Ge, Qin, Jian-Hua, Hu, Pu-Zhou
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977568/
https://www.ncbi.nlm.nih.gov/pubmed/21583754
http://dx.doi.org/10.1107/S1600536809012975
Descripción
Sumario:In the title compound, [AgCl(C(2)H(2)N(2)S(2))](n), the Ag(I) ion has a distorted tetra­hedral geometry, defined by two S atoms of two symmetry-related 1,3,4-thia­diazo­lium-2-thiol­ate ligands and two chloride ions. The Ag(I) ions are bridged into a two-dimensional network parallel to the ab plane by chloride ions and thia­diazole ligands. In the network, the Ag(I) ions are separated by 4.0316 (12) Å along the a axis and by 4.8822 (13) Å along the b axis. N—H⋯Cl hydrogen bonds are observed within the network.

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