Poly[di-μ(2)-acetato-diaquabis(2,2′-bi­pyridine)bis(μ(3)-5-nitroisophthalato)tricobalt(II)]

The title complex, [Co(3)(C(8)H(3)NO(6))(2)(C(2)H(3)O(2))(2)(C(10)H(8)N(2))(2)(H(2)O)(2)], was synthesized under hydro­thermal conditions. The structure features a centrosymmetric complex with three Co(II) centres, one of which is located on a centre of inversion. The Co centres are coordinated in a...

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Detalles Bibliográficos
Autores principales: Wang, Hai-Dong, Li, Min-Min, He, Hong-Yin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977571/
https://www.ncbi.nlm.nih.gov/pubmed/21583757
http://dx.doi.org/10.1107/S1600536809012562
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author Wang, Hai-Dong
Li, Min-Min
He, Hong-Yin
author_facet Wang, Hai-Dong
Li, Min-Min
He, Hong-Yin
author_sort Wang, Hai-Dong
collection PubMed
description The title complex, [Co(3)(C(8)H(3)NO(6))(2)(C(2)H(3)O(2))(2)(C(10)H(8)N(2))(2)(H(2)O)(2)], was synthesized under hydro­thermal conditions. The structure features a centrosymmetric complex with three Co(II) centres, one of which is located on a centre of inversion. The Co centres are coordinated in a distorted octa­hedral geometry. The bipyridine ligands are bonded to just one Co centre in a chelating mode, whereas the 5-nitro­isophthalate and acetate ions are bonded to two different Co atoms. The crystal structure is stabilized by O—H⋯O hydrogen bonds.
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spelling pubmed-29775712010-12-30 Poly[di-μ(2)-acetato-diaquabis(2,2′-bi­pyridine)bis(μ(3)-5-nitroisophthalato)tricobalt(II)] Wang, Hai-Dong Li, Min-Min He, Hong-Yin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Co(3)(C(8)H(3)NO(6))(2)(C(2)H(3)O(2))(2)(C(10)H(8)N(2))(2)(H(2)O)(2)], was synthesized under hydro­thermal conditions. The structure features a centrosymmetric complex with three Co(II) centres, one of which is located on a centre of inversion. The Co centres are coordinated in a distorted octa­hedral geometry. The bipyridine ligands are bonded to just one Co centre in a chelating mode, whereas the 5-nitro­isophthalate and acetate ions are bonded to two different Co atoms. The crystal structure is stabilized by O—H⋯O hydrogen bonds. International Union of Crystallography 2009-04-10 /pmc/articles/PMC2977571/ /pubmed/21583757 http://dx.doi.org/10.1107/S1600536809012562 Text en © Li et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Hai-Dong
Li, Min-Min
He, Hong-Yin
Poly[di-μ(2)-acetato-diaquabis(2,2′-bi­pyridine)bis(μ(3)-5-nitroisophthalato)tricobalt(II)]
title Poly[di-μ(2)-acetato-diaquabis(2,2′-bi­pyridine)bis(μ(3)-5-nitroisophthalato)tricobalt(II)]
title_full Poly[di-μ(2)-acetato-diaquabis(2,2′-bi­pyridine)bis(μ(3)-5-nitroisophthalato)tricobalt(II)]
title_fullStr Poly[di-μ(2)-acetato-diaquabis(2,2′-bi­pyridine)bis(μ(3)-5-nitroisophthalato)tricobalt(II)]
title_full_unstemmed Poly[di-μ(2)-acetato-diaquabis(2,2′-bi­pyridine)bis(μ(3)-5-nitroisophthalato)tricobalt(II)]
title_short Poly[di-μ(2)-acetato-diaquabis(2,2′-bi­pyridine)bis(μ(3)-5-nitroisophthalato)tricobalt(II)]
title_sort poly[di-μ(2)-acetato-diaquabis(2,2′-bi­pyridine)bis(μ(3)-5-nitroisophthalato)tricobalt(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977571/
https://www.ncbi.nlm.nih.gov/pubmed/21583757
http://dx.doi.org/10.1107/S1600536809012562
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AT liminmin polydim2acetatodiaquabis22bipyridinebism35nitroisophthalatotricobaltii
AT hehongyin polydim2acetatodiaquabis22bipyridinebism35nitroisophthalatotricobaltii

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