Bis(4-amino-3,5-di-2-pyridyl-4H-1,2,4-triazole)diaquanickel(II) bis(perchlorate)

In the mol­ecular structure of the centrosymmetric mononuclear complex [Ni(2-bpt)(2)(H(2)O)(2)](ClO(4))(2) [2-bpt = 4-amino-3,5-di-2-pyridyl-1,2,4-triazole, (C(12)H(10)N(6))], the central Ni(II) atom is six-coordinated by a pair of chelating 2-bpt ligands and two water mol­ecules. Inter­molecular O—...

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Detalles Bibliográficos
Autores principales: Shao, Chun-Fu, Geng, Li-Chuan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977572/
https://www.ncbi.nlm.nih.gov/pubmed/21583758
http://dx.doi.org/10.1107/S1600536809012598
Descripción
Sumario:In the mol­ecular structure of the centrosymmetric mononuclear complex [Ni(2-bpt)(2)(H(2)O)(2)](ClO(4))(2) [2-bpt = 4-amino-3,5-di-2-pyridyl-1,2,4-triazole, (C(12)H(10)N(6))], the central Ni(II) atom is six-coordinated by a pair of chelating 2-bpt ligands and two water mol­ecules. Inter­molecular O—H⋯N inter­actions link the monomeric units into a two-dimensional hydrogen-bonded (4,4) network, which is extended to a three-dimensional supra­molecular aggregate via π⋯π stacking inter­actions [centroid–centroid distances 3.809 (3) and 3.499 (3)  Å].

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